现代纺织技术 ›› 2025, Vol. 33 ›› Issue (11): 19-26.DOI: 10.12477/j.att.202408049

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固/液金属图案化复合传感的玉米醇溶蛋白超细纤维基LC应变传感器

陈焕,丁润龙,刘飞,肖雅,崔丽娜,蒋秋冉   

  1. 1.东华大学,a.纺织面料技术教育部重点实验室;b.纺织学院,上海 201620;2.泉州师范学院纺织与服装学院,福建泉州 362000
  • 出版日期:2025-11-18 网络出版日期:2025-11-18
  • 基金资助:
    中央高校基本科研业务费专项资金项目(2232022D-13); 2022年泉州市“揭榜挂帅”科技重大专项目(2022GZ4)

ZE ultrafine fibrous LC strain sensors with solid-liquid metal composite patterning sensing layer

CHEN Huan, DING Runlong, LIU Fei, XIAO Ya, CUI Lina, JIANG Qiuran   

  1. 1a. Key Laboratory of Textile Science & Technology, Ministry of Education; b. College of Textiles, Donghua University, Shanghai 201620, China; 2. College of Textile and Apparel, Quanzhou Normal University, Quanzhou 362000, China
  • Published:2025-11-18 Online:2025-11-18

摘要: 为克服电感-电容应变传感器难以兼顾高灵敏度和宽工作范围的问题,利用丝网印刷银浆溶液和掩膜喷涂沉积液态金属技术,将传感层的固态银与液态金属进行图案化结合,在玉米醇溶蛋白超细纤维基底上构建固液金属复合传感层,实现了高灵敏和宽工作范围的柔性LC应变传感器的制备。研究表明:银和液态金属复合的柔性传感器能够改善单一材料传感器的传感性能;相较于纯银,固液金属复合传感器工作范围提升了122%;相较于纯液态金属,灵敏度提升了300%。此外,固液金属比例的变化显著影响传感器的传感性能,其中面积比为2∶1的银/液态金属比例表现出良好的灵敏度(28.6 MHz/𝜀)和可接受的工作应变范围(82%)。基于玉米醇溶蛋白超细纤维基底,固液金属复合传感器具有高透气等良好的性能,可用于医疗诊断、生物监测等多种应用场景。

关键词: LC应变传感器, 丝网印刷, 银, 液态金属, 玉米醇溶蛋白超细纤维

Abstract: Biological flexible sensors can monitor the wearer's health and environment in real time, attracting significant academic interests. They have broad potential applications in areas such as medical diagnostics and fitness monitoring. However, traditional biological flexible sensors usually require cables to connect to external devices, making them complex, bulky, and short-lived. Especially for implanted active sensors, the need for regular battery replacement can cause additional harm to patients. Passive wireless sensors, on the other hand, do not require power connections, electrodes, or wires. They are lightweight, compact, simple in structure, and have a longer lifespan. LC resonant sensors, which are inductive field sensors, have a simpler structure compared to harmonic sensors, as they do not require diodes. Both solid and liquid metals are widely used to construct the sensing layer of sensors. Solid metals can offer high sensitivities but are brittle, limiting the sensor's working range. Liquid metals (LM), with their high flexibility, fluidity, and conductivity, can adapt to complex shapes and dynamic environments, providing a broader operational range but limited sensitivity. To achieve both high sensitivity and a broad working range in flexible LC passive wireless strain sensors, this study employs screen printing and mask spraying techniques to construct a patterned solid-liquid metal composite sensing layer on a ZE ultrafine fiber substrate. By combining the sensing advantages of solid and liquid metals, the sensor's performance is optimized. ZE ultrafine fibers are an ideal biomedical flexible substrate due to their natural flexibility, high surface area, biocompatibility, and biodegradability. A planar spiral sensing coil is formed by combining screen-printed solid silver (Ag) with mask-sprayed liquid metal in a segmented pattern, integrated with the ultrafine fiber substrate. The screen printing and spraying processes are simple, low-cost, and allow for rapid patterning of the sensing layer. Experimental results show that the choice of sensing layer materials and the solid/liquid metal ratio significantly impact the sensor's initial resistance and sensitivity. The optimal Ag/LM ratio is 2:1, balancing sensitivity (28.6 MHz) and operational range (82%). The study also examines how the sensor's microstructure and porosity affect its gas permeability. The results indicate that the Ag/LM composite design not only enhances the sensor's performance but also maintains breathability, making it suitable for biomedical applications that require high comfort and functionality. The combination of degradable ZE substrate and unique solid-liquid metal composite design gives this sensor potential applications in biomedical monitoring, environmental sensing, and wearable devices. The research integrates the advantages of solid and liquid metals into a single sensing layer, offering a new approach to developing flexible strain biological sensors.

Key words: LC strain sensor, screen printing, silver, liquid metal, ZE ultrafine fibers

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