二维材料MXene(Ti3C2Tx)的制备、性能及其在纺织领域中的应用

doi:10.19398/j.att.202105030

摘要/Abstract

摘要：

为进一步推动MXene (Ti₃C₂T_x)在纺织领域中功能化和智能化方面的应用,结合国内外相关文献,着重介绍MXene的制备方法,包括HF腐蚀法、原位产生HF腐蚀法、熔融盐法、电化学法、浓碱法等;详细综述了MXene在纺织领域的力学、电学、阻燃抑烟、储能等方面的研究进展;总结了MXene在以纺织油墨、纤维、涂层等为载体的智能织物和柔性传感器等应用中的优异性能。最后指出了MXene在树脂基体中分散性较差,在空气中易被氧化和使用耐久性等不足及其未来发展方向。

关键词: 二维材料, MXene, 制备, 性能, 纺织材料, 应用

Abstract:

To facilitate the functional and intelligent application of MXene (Ti₃C₂T_x)in textile realted field, relevant domestic and foreign literature were reviewed to specifically elaborate on the preparation methods of MXene, including HF corrosion method, in situ-generated HF corrosion method, molten salt method, electrochemical process, and concentrated alkali method; the research progress of MXene in textile fields related to mechanics, electricity, flame retardant smoke suppression, energy storage were summarized in detail; the outstanding performance of MXene in intelligent fabrics and flexible sensors based on textile inks, fibers, and coating were concluded. Finally, this paper indicated the inadequacies of MXene such as poor dispersity in the resin matrix, the susceptibility to oxidation in the air, poor durability of use, as well as its future direction of development.

Key words: two-dimensional material, MXene, preparation, property, textile materials, application

中图分类号:

TS102.6

严小飞, 方杰, 朱晨凯, 李家炜, 祝成炎, 戚栋明. 二维材料MXene(Ti₃C₂T_x)的制备、性能及其在纺织领域中的应用[J]. 现代纺织技术, 2022, 30(2): 1-8.

YAN Xiaofei, FANG Jie, ZHU Chenkai, LI Jiawei, ZHU Chengyan, QI Dongmin. Preparation and properties of two-dimensional material MXene (Ti₃C₂T_x)and Its application in textile field[J]. Advanced Textile Technology, 2022, 30(2): 1-8.

图/表 5

图1 MXene结构及其在织物中的各种功能应用[31]

Fig.1 MXene structure and its various functional applications in fabrics[31]

图2 MXene油墨在织物上印刷的过程[32]

Fig.2 The printing process of MXene ink on fabric[32]

图3 MXene改性纤维制成多功能的智能织物[38]

Fig.3 Multifunctional intelligent fabric made of MXene modified fibers[38]

图4 MXene与ZnO、Ni在织物上构建杂化纳米结构流程图[41]

Fig.4 Flow chart of constructing hybrid nanostructures on fabrics by MXene, ZnO and Ni[41]

图5 在棉织物上构建涂层的过程[44]

Fig.5 The process of constructing coating on cotton fabric[44]

参考文献 46

[1]	NAGUIB M, MOCHALIN V N, BARSOUM M W, et al. MXenes: A new family of two-dimensional materials[J]. Advanced Materials, 2014, 26(7):992-1005. DOI URL
[2]	SHARMA G, MUTHUSWAMY E, NAGUIB M, et al. Calorimetric study of alkali metal Ion (K⁺, Na⁺, Li⁺)exchange in a clay-like MXene[J]. Journal of Physical Chemistry C, 2017, 121(28):15145-15153. DOI URL
[3]	丁小惠, 李春虎, 王文泰, 等. 磁性光催化剂TiO₂/Ti₃C₂/Fe₃O₄的制备及光催化Fenton降解苯胺[J]. 中国海洋大学学报(自然科学版), 2019, 49(12):67-74.
	DING Xiaohui, LI Chunhu, WANG Wentai, et al. Preparation of TiO₂/Ti₃C₂/Fe₃O₄ magnetic photocatalytst and the photocatalytic degradation of aniline[J]. Periodical of Ocean University of China, 2019, 49(12):67-74.
[4]	SHARMA G, NAGUIB M, FENG D, et al. Calorimetric determination of thermodynamic stability of MAX and MXene phases[J]. The Journal of Physical Chemistry C, 2016, 120(49):28131-28137. DOI URL
[5]	SHI Y, LIU C, DUAN Z, et al. Interface engineering of MXene towards super-tough and strong polymer nanocomposites with high ductility and excellent fire safety[J]. Chemical Engineering Journal, 2020, 399:125829. DOI URL
[6]	秦文峰, 符佳伟, 刘国春, 等. Ti₃C₂T_x MXene负载玻璃纤维材料制备与电磁屏蔽性能[J]. 稀有金属材料与工程, 2020, 49(11):3896-3901.
	QIN Wenfeng, FU Jiawei, LIU Guochun, et al. Preparation and electromagnetic shielding properties of Ti₃C₂T_x MXene/glass fiber composites[J]. Rare Metal Materials and Engineering, 2020, 49(11):3896-3901.
[7]	BOOTA M, GOGOTSI Y. MXene-conducting polymer asymmetric pseudocapacitors[J]. Advanced Energy Materials, 2019, 9(7):1802917. DOI URL
[8]	MAYERBERGER E A, URBANEK O, MCDANIEL R M, et al. Preparation and characterization of polymer-Ti₃C₂T_x (MXene)composite nanofibers produced via electrospinning[J]. Journal of Applied Polymer Science, 2017, 134(37):45295. DOI URL
[9]	GUND G S, PARK J H, HARPALSINH R, et al. MXene/polymer hybrid materials for flexible ac-filtering electrochemical capacitors[J]. Joule, 2019, 3(1):164-176. DOI URL
[10]	NAGUIB M, SAITO T, LAI S, et al. Ti₃C₂T_x(MXene)-polyacrylamide nanocomposite films[J]. RSC Advances, 2016, 6(76):72069-72073. DOI URL
[11]	GAO L, LI C, HUANG W, et al. MXene/polymer membranes: Synjournal, properties, and emerging applications[J]. Chemistry of Materials, 2020, 32(5):1703-1747. DOI URL
[12]	YAN J, REN C E, HATTER C, et al. Flexible MXene/graphene films for ultrafast supercapacitors with outstanding volumetric capacitance[J]. Advanced Functional Materials, 2017, 27(30):1701264. DOI URL
[13]	NAGUIB M, HALIM J, LU J, et al. New two-dimensional niobium and vanadium carbides as promising materials for Li-ion batteries[J]. Journal of the American Chemical Society, 2013, 135(43):15966-15969. DOI URL
[14]	ANASORI B, LUKATSKAYA M R, GOGOTSI Y. 2D metal carbides and nitrides (MXenes)for energy storage[J]. Nature Reviews Materials, 2017, 2:16098. DOI URL
[15]	康瑞洋, 张振宇, 郭梁超, 等. Ti₃C₂ MXene填充环氧树脂复合材料摩擦学性能研究[J]. 硬质合金, 2019, 36(3):213-220.
	KANG Ruiyang, ZHANG Zhenyu, GUO Liangchao, et al. Study on the tribological property of epoxy composites filled with Ti₃C₂ MXene[J]. Cemented Carbide, 2019, 36(3):213-220.
[16]	MICHAEL N, MURAT K, VOLKER P, et al. Two-dimensional nanocrystals produced by exfoliation of Ti₃AlC₂[J]. Advanced Materials, 2011, 23(37):4248-4253. DOI URL
[17]	GHIDIU M, LUKATSKAYA M R, ZHAO M Q, et al. Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance[J]. Nature, 2014, 516(7529):78-81. DOI URL
[18]	FENG A, YU Y, WANG Y, et al. Two-dimensional MXene Ti₃C₂ produced by exfoliation of Ti₃AlC₂[J]. Materials & Design, 2017, 114:161-166.
[19]	LI T, YAO L, LIU Q, et al. Fluorine-free synjournal of high-purity Ti₃C₂T_x (T=OH, O)via alkali treatment[J]. Angewandte Chemie, 2018, 130(21):6223-6227. DOI URL
[20]	NAGUIB M, PRESSER V, TALLMAN D, et al. On the topotactic transformation of Ti₂AlC into a Ti-C-O-F cubic phase by heating in molten lithium fluoride in air[J]. Journal of the American Ceramic Society, 2011, 94(12):4556-4561. DOI URL
[21]	SEYEDIN S, UZUN S, LEVITT A, et al. MXene composite and coaxial fibers with high stretchability and conductivity for wearable strain sensing textiles[J]. Advanced Functional Materials, 2020, 30(12):1910504. DOI URL
[22]	TALOUB N, HENNICHE A, LIU L, et al. Improving the mechanical properties, UV and hydrothermal aging resistance of PIPD fiber using MXene (Ti₃C₂(OH)₂)nanosheets[J]. Composites Part B: Engineering, 2019, 163:260-271. DOI URL
[23]	CHEN L, CAO Y, GUO X, et al. Simultaneously improved thermal and dielectric performance of epoxy composites containing Ti₃C₂T_x platelet fillers[J]. Polymers, 2020, 12(7):1608. DOI URL
[24]	SONG P, QIU H, WANG L, et al. Honeycomb structural rGO-MXene/epoxy nanocomposites for superior electromagnetic interference shielding performance[J]. Sustainable Materials and Technologies, 2020, 24:e00153. DOI URL
[25]	PAN Y, FU L, ZHOU Q, et al. Flammability, thermal stability and mechanical properties of polyvinyl alcohol nanocomposites reinforced with delaminated Ti₃C₂T_x (MXene)[J]. Polymer Composites, 2020, 41(1):210-218. DOI URL
[26]	HUANG H, DONG D, LI W, et al. Synergistic effect of MXene on the flame retardancy and thermal degradation of intumescent flame retardant biodegradable poly (lactic acid)composites[J]. Chinese Journal of Chemical Engineering, 2020, 28(7):1981-1993. DOI URL
[27]	MASHTALIR O, LUKATSKAYA M R, ZHAO M Q, et al. Amine-assisted delamination of Nb₂C MXene for Li-Ion energy storage devices[J]. Advanced Materials, 2015, 27(23):3501-3506. DOI URL
[28]	XIONG D, LI X, BAI Z, LU S. Recent advances in layered Ti₃C₂T_x MXene for electrochemical energy storage[J]. Small, 2018, 14(17):1703419. DOI URL
[29]	QIN L, TAO Q, LIU X, et al. Polymer-MXene composite films formed by MXene-facilitated electro-chemical polymerization for flexible solid-state microsu-percapacitors[J]. Nano Energy, 2019, 60:734-742. DOI URL
[30]	WU X, HUANG B, LV R, et al. Highly flexible and low capacitance loss supercapacitor electrode based on hybridizing decentralized conjugated polymer chains with MXene[J]. Chemical Engineering Journal, 2019, 378:122246. DOI URL
[31]	ABBAS A M, BAPAN A, SAMRAT M. Recent advances in 2D MXene integrated smart-textile interfaces for multifunctional applications[J]. Chemistry of Materials, 2020, 32(24):10296-10320. DOI URL
[32]	UZUN S, SCHELLING M, HANTANASIRISAKUL K, et al. Additive-free aqueous MXene inks for thermal inkjet printing on textiles[J]. Small, 2021, 17(1):2006376. DOI URL
[33]	ZHANG C J, MCKEON L, KREMER M P, et al. Additive-free MXene inks and direct printing of micro-supercapacitors[J]. Nature Communications, 2019, 10:1795. DOI URL
[34]	CAO W T, MA C, MAO D S, et al. MXene-reinforced cellulose nanofibril inks for 3D-printed smart fibres and textiles[J]. Advanced Functional Materials, 2019, 29(51):1905898. DOI URL
[35]	KAUSHIK V, LEE J, HONG J, et al. Textile-based electronic components for energy applications: Principles, problems, and perspective[J]. Nanomaterials, 2015, 5(3):1493-1531. DOI URL
[36]	ISMAR E, BAHADIR S K, KALAOGLU F, et al. Futuristic clothes: Electronic textiles and wearable tech-nologies[J]. Global Challenges, 2020, 4(7):1900092. DOI URL
[37]	LIU R, LI J, LI M, et al. MXene-coated air-permeable pressure-sensing fabric for smart wear[J]. ACS Applied Materials & Interfaces, 2020, 12(41):46446-46454.
[38]	LEVITT A, ZHANG J Z, DION G, et al. MXene-based fibers, yarns, and fabrics for wearable energy storage devices[J]. Advanced Functional Materials, 2020, 30(47):2000739. DOI URL
[39]	SEYEDIN S, ZHANG J, USMAN K, et al. Facile solution processing of stable MXene dispersions towards conductive composite fibers[J]. Global Challenges, 2019, 3(10):1900037. DOI URL
[40]	李一飞, 郑敏, 常朱宁子, 等. 二维过渡金属碳化物(Ti₃C₂T_x)对棉针织物的功能整理及其性能分析[J]. 纺织学报, 2021, 42(6):120-127.
	LI Yifei, ZHENG Min, CHANGZHU Ningzi, et al. Cotton knitted fabrics treated with two-dimensional transi-tional metal carbide Ti₃C₂T_x and property analysis[J]. Journal of Textile Research, 2021, 42(6):120-127.
[41]	WANG S, LI D, ZHOU Y, et al. Hierarchical Ti₃C₂T_xMXene/Ni chain/ZnO array hybrid nanostructures on cotton fabric for durable self-cleaning and enhanced microwave absorption[J]. ACS Nano, 2020, 14(7):8634-8645. DOI URL
[42]	WANG S, DU X, LUO Y, et al. Hierarchical design of waterproof, highly sensitive, and wearable sensing electronics based on MXene-reinforced durable cotton fabrics[J]. Chemical Engineering Journal, 2021, 408:127363. DOI URL
[43]	SEYEDIN S, YANZA E, RAZAL J M. Knittable energy storing fiber with high volumetric performance made from predominantly MXene nanosheets[J]. Journal of Materials Chemistry A, 2017, 5(46):24076-24082. DOI URL
[44]	YAN J, MA Y, ZHANG C, et al. Polypyrrole-MXene coated textile-based flexible energy storage device[J]. RSC Advances, 2018, 8(69):39742-39748. DOI URL
[45]	WANG Y, QI Q, FAN J, et al. Simple and robust MXene/carbon nanotubes/cotton fabrics for textile wastewater purification via solar-driven interfacial water evaporation[J]. Separation and Purification Technology 2021, 254:117615. DOI URL
[46]	RAAGULAN K, BRAVEENTH R, JANG H J, et al. Electromagnetic shielding by MXene-graphene-PVDF composite with hydrophobic, lightweight and flexible graphene coated fabric[J]. Materials, 2018, 11(10):1803. DOI URL

二维材料MXene(Ti₃C₂T_x)的制备、性能及其在纺织领域中的应用

Preparation and properties of two-dimensional material MXene (Ti₃C₂T_x)and Its application in textile field

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