疏水亲油复合棉织物的制备及其性能

doi:10.19398/j.att.202107001

摘要/Abstract

摘要： 为促进绿色油污吸附材料的研制,以纯棉机织物、毛巾织物为基体,采用浸渍法引入二氧化硅纳米颗粒增加表面粗糙度,通过长链烷烃疏水基团降低表面能,获得疏水亲油棉织物。采用机织物/毛巾织物3－5层的层间复合方式制备疏水亲油复合型棉织物,并对其吸油倍数、保油率、吸油总量进行测试与分析。结果表明:复合型棉织物吸油性能得到提高,复合方式影响其吸油性能。毛巾织物复合在外层时,吸油倍数和吸油总量高,外层织物为机织物复合时,保油率高。疏水亲油复合型棉织物对原油的吸油倍数、保油率最高分别为206%、89.6%。

关键词: 棉织物, 疏水亲油, 二氧化硅纳米颗粒, 复合棉织物

Abstract: In order to advance the development of green oil pollution adsorption materials, we used impregnation method by introducing silica nanoparticles to strenghten the surface roughness and long-chain alkane hydrophobic groups to reduce the surface energy based on cotton woven fabrics and cotton towel fabric, obtaining hydrophobic-oleophylic cotton fabrics. We prepared the hydrophobic-oleophylic cotton fabrics with an alternative use of 3-5 layers of cotton woven fabric and cotton towel fabric, tested and analyzed their oil absorption capacity, oil retention rate as well as total oil absorption. As a result, the oil absorption performance of composite cotton fabrics is improved, which indicates that the composite mode affects the oil absorption performance. When the towel fabric is laminated on the outer layer, the oil absorption capacity and total oil absorption are high; otherwise, the retention rate is high. The highest oil absorption capacity and oil retention rate of the hydrophobic-lipophilic composite cotton fabrics to crude oil are respectively 206% and 89.6%.

Key words: cotton fabric, hydrophobic-oleophylic, silica nanoparticles, composite cotton fabrics

中图分类号:

TB332

陈春晖, 许多, 李治江, 吉强. 疏水亲油复合棉织物的制备及其性能[J]. 现代纺织技术, 2022, 30(4): 115-123.

SCHEN Chunhui, XU Duo, LI Zhijiang, JI Qiang. Preparation and properties of hydrophobic-oleophylic composite cotton fabrics[J]. Advanced Textile Technology, 2022, 30(4): 115-123.

参考文献

[1] 曾燕萍,安振.“一带一路”新形势下中国石油运输安全战略研究[J].国际经济合作,2018(1):68-74.
ZENG Yanping, AN Zhen. Research on China's petroleum transportation security strategy under the new situation of "One Belt and One Road"[J]. Journal of International Economic Cooperation, 2018, (1): 68-74.
[2] 刘彩云.海洋溢油事件的生态风险评估方法比较研究[J].科技视界,2016(3):73.
LIU Caiyun. Comparative study on ecological risk assessment methods for Marine oil spill events[J]. Science & Technology Vision, 2016(3): 73.
[3] 杨双华,邵高耸,卢林刚.常见吸油材料的研究进展及展望[J].应用化工,2019,48(4):926-931,937.
YANG Shuanghua, SHAO Gaosong, LU Lingang. Progress and prospect of common oil adsorption materials[J]. Applied Chemical Industry, 2019, 48(4):926-931,937.
[4] 罗冬,谢翼飞,谭周亮,等.NaOH改性玉米秸秆对石油类污染物的吸附研究[J].环境科学与技术,2014,37(1):28-32,42.
LUO Dong, XIE Yifei, TAN Zhouliang, et al. Optimization of NaOH modified corn stalk and its adsorption of petroleum pollutants[J]. Environmental Science & Technology, 37(1): 28-32, 42.
[5] 王帅,杨晨曦.疏水/亲油改性柚子皮纤维的制备及其性能研究[J].应用化工,2019,48(6):1321-1325.
WANG Shuai, YANG Chenxi. Preparation and properties of hydrophobic/lipophilic modified grapefruit fiber[J]. Applied Chemical Industry, 2019, 48(6):1321-1325.
[6] 户岐飞,王晓丽,彭士涛,等.疏水亲油苎麻纤维吸油材料的制备及其性能[J].石油化工安全环保技术,2018,34(3):60-64,70.
HU Qifei, WANG Xiaoli, PENG Shitao, et al. Preparation and performance of modifided ramie fiber etth hydrophobic and oleophylic properties[J]. Petrochemical Safety and Environmental Protection Technology, 2018, 34(3): 60-64, 70.
[7] 王海娇.基于玉米秸秆吸油材料的制备及性能研究[D].哈尔滨:哈尔滨工业大学,2015.
WANG Haijiao. Study on Preparation and Properties of Oil-Absorbing Material Based on Corn Straw[D]. Harbin: Harbin Institute of Technology, 2015.
[8] LIU F, MA M, ZANG D, etal. Fabrication of superhydrophobic/superoleophilic cotton forapplication in the field of water/oil separation[J].Carbohydrate Polymers, 2014, 103: 480-487.
[9] 由晗杨,张毅,李文英,等.氯型季胺特种树脂吸附地下水NO^-₃的动力学和热力学[J].工业水处理,2020,40(4):49-54.
YOU Hanyang, ZHANG Yi, LI Wenying, etal. Sorption kinetics and thermodynamics study of NO^-₃ in groundwater by chlorinated quaternary amine special resin[J]. Industrial Water Treatment, 2020, 40(4): 49-54.
[10] 杨啸天,帅茜,罗艳梅,等.聚二甲基硅氧烷/微纳米银/聚多巴胺修饰的超疏水海绵的制备和应用[J].应用化学,2015,32(6):726-732.
YANG Xiaotian, SHUAI Qian, LUO Yangmei,etal. Fabrication and application of the superhydrophobic sponge modified with poly (dimethylsiloxane)/silver micro/nano-particles/polydopamine[J]. Chinese Journal of Applied Chemistry, 2015, 36(6): 726-732.
[11] XI Z, JIANG M, YANG J,et al.Experimentalstudy on advantages of foam-sol in coal dust control[J].Process Safety and Environmental Protection,2014,92(6): 637-644.

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