关键词: 栀子黄植物染料, 真丝, 藏红花素Ⅰ, 藏红花酸, 鉴别

Abstract: In recent years, with the improvement of people's awareness of environmental protection, ecological textiles have been increasingly favored by people. Because of their non-toxic, biodegradable and other characteristics, plant dyes are widely used to study the dyeing and printing of textiles. Dyeing and printing with plant dyes can not only reduce the harm of dyes to the human body and make full use of natural renewable resources, but also greatly reduce the toxicity of printing and dyeing wastewater, playing a role in protecting the environment indirectly. At present, the development and utilization of plant dyes is under the active exploration and research, and the plant dye demonstration system engineering has been launched officially. In order to fill the deficiency of the world plant dye standard system, and lay a solid foundation for China to lead the development of the global plant dye industry, it is necessary to establish the identification methods and standards of plant dye series of products. In order to ensure the quality of plant dyeing products on the market, crack down on fake and shoddy products, and standardize market operation, so that consumers can rest assured and buy satisfactory plant dyeing products, it is very important to identify the corresponding vegetable dyes and dyeing textiles.
In order to identify plant dyes and their dyed textiles, this paper takes gardenia yellow plant dyes and dyed silk fabrics as the research objects. Firstly, the gardenia yellow plant dyes were tested by ultraviolet spectrophotometer, and the markers of gardenia yellow plant dyes were indentified by combining with the descriptions in the literature. Then the markers, gardenia yellow plant dyes and their dyed silk fabric extract were detected by using liquid mass combination instrument under negative ion mode. By comparing the retention time and mass spectrometry of the dyes, dyed silk fabric extract and the dyed silk fabric, whether the dye and fabric were gardenia yellow plant dye and its dyed silk fabric was determined.
The results showed that crocin Ⅰ and crocin acid could be used as markers to distinguish gardenia yellow plant dyes and their dyed silk fabrics. The molecular ion peaks m/z=975.3472 and m/z=327.1553 were detected in the mass spectrum of gardenia yellow plant dyes, and the retention times were 0.61 min and 1.38 min, respectively. The molecular ion peaks m/z=975.396 and m/z=327.1489 were detected in the mass spectrum of dyed silk fabric extract, and the retention times were 0.61 min and 1.38 min, respectively. The retention times were similar to the peak time of the crocin Ⅰ standard substance (0.61 min) and crocin acid standard substance (1.36 min), and the deviations were within the allowable deviation range of ±2.5%. Therefore, it was determined that the dye and the dyed silk fabric are respectively the gardenia yellow plant dye and its dyed silk fabric.
At present, many textile colleges and universities have established relatively complete database of vegetable dyes and comprehensive vegetable dye color cards. However, there are certain deficiencies in the relevant standards of plant dyeing in every link in the current market, and consumers have insufficient awareness of them and cannot verify the conformity of products. Therefore, identifying the corresponding plant dyes and their dyed fabrics is a priority in the development of plant dyeing.

Key words: gardenia yellow vegetable dye, real silk, crocinⅠ, croctin acid, identification