现代纺织技术 ›› 2025, Vol. 33 ›› Issue (02): 83-89.

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氮化铝凉感涤纶织物的防紫外线整理效果及评价

  

  1. 1.浙江理工大学桐乡研究院有限公司,浙江桐乡 314500;2.浙江理工大学纺织科学与工程学院(国际丝绸学院),杭州 310018
  • 出版日期:2025-02-10 网络出版日期:2025-02-24

Effect and evaluation of UV-resistant finishing of cool-feeling aluminum nitride polyester fabrics

  1. 1. Zhejiang Sci-Tech University Tongxiang Research Institute, Tongxiang 314500, China; 2. College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou 310018, China
  • Published:2025-02-10 Online:2025-02-24

摘要: 为开发凉感涤纶织物并评价其防紫外线整理效果,首先制备了氮化铝改性的聚酯纤维,再选用不同的防紫外线整理剂,采用一浸一轧法对织造得到的凉感涤纶织物进行防紫外线整理。通过比较自研的TQ-100防紫外线整理剂与常规市售的防紫外线整理剂的整理效果,对比分析凉感涤纶织物整理前后的表面形貌、导热性能、耐水洗性、透气性、紫外光照耐受性,发现防紫外线整理剂对凉感涤纶织物的凉感效果、防紫外线的耐洗持久性、透气性以及紫外光照耐受性产生了显著影响。研究表明:TQ-100整理剂在应用中显著提高了凉感涤纶织物的凉感效果,同时赋予了织物出色的耐洗持久性和紫外光照耐受性,且该整理剂在适当的工艺条件下,对织物的透气性影响微乎其微。此外,研究还表明,对于氮化铝凉感涤纶类织物,采用无机纳米材料和有机防紫外材料复配的助剂进行防紫外线整理更为有效。

关键词: 凉感涤纶, 防紫外整理, 导热系数, UPF, UVA, 耐洗, 透气性

Abstract: In the context of global warming, the heat of summer and the intense ultraviolet radiation have become a problem that cannot be ignored in people's Daily life. It has become particularly important for textiles to meet people's needs for coolness, comfort, protection against UV burning and tanning. Therefore, the research and development of textiles with these functions has become an important topic in the textile industry. In response to this demand, we have deeply studied the processing methods of cool textiles and UV-resistant textiles. First of all, we focus on reducing the thermal resistance of textiles, improving the thermal conductivity, so that the heat generated by the human body can be quickly released and discharged, the stuffy feeling of the human body can be overcome and the comfort of wearing can be improved. To this end, we modified the fiber raw materials with aluminum nitride and spun it successfully to make cool-feeling polyester fabrics.
At present, the commonly used ultraviolet finishing agents in the domestic market are mainly organic ultraviolet absorbers based on benzophenone and benzotriazole compounds, and they are suitable for anti-ultraviolet finishing of all kinds of clothing fabrics, giving clothing fabrics excellent anti-ultraviolet properties. Inorganic substances have refractivity and optical activity to incident light, and ultraviolet scatters mainly utilize this feature to reflect and scatter ultraviolet light to varying degrees. These substances are metals, metal oxides and their salts, such as titanium dioxide, silicon dioxide, iron oxide and carbon black. Nanoscale UV scattering particles, which can also absorb ultraviolet rays and have stronger blocking ability against ultraviolet rays, have become an important material for the development of anti-ultraviolet finishing agents.
Considering the particularity of AlN cool-feeling modified polyester fabrics, we adopted an innovative method to prepare a UV protective finishing agent TQ-100 by combining nano inorganic dispersion with organic UV absorbent. We used one dip and one roll finishing method to treat the cool polyester fabric with UV protection, and compared it with common UV protection finishing agents sold in the market. Through testing, comparison and analysis of the surface morphology, thermal conductivity, washable resistance, air permeability and UV light resistance of the cool-feeling polyester fabrics before and after finishing, we have drawn the following conclusions: the TQ-100 finishing agent can significantly improve the cool-feeling effect of the polyester fabric, and has good durability and UV light resistance. At the same time, the finishing agent has little effect on the air permeability of the fabric under proper usage amount. The results show that it is a more reasonable method to finish AlN cool polyester fabric with agent combined inorganic nanomaterials with mechanical UV-resistant materials. This not only meets people's needs for coolness and UV protection, but also ensures the fabric's air permeability and durability. We believe that this research result will have great guiding significance for the UV and suntan protection finishing of cool textiles in summer.

Key words: cool-feeling polyester, UV-resistant finishing, thermal conductivity, UPF, UVA, washable, air permeability

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