现代纺织技术 ›› 2025, Vol. 33 ›› Issue (05): 75-85.

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水性涂料色浆的制备及其在窗帘织物中的应用

  

  1. 1.浙江理工大学纺织科学与工程学院(国际丝绸学院),杭州 310018;
    2.现代纺织技术创新中心(鉴湖实验室),浙江绍兴 312030;
    3.浙江省绿色清洁技术及洗涤用品重点实验室,浙江丽水 323000
  • 出版日期:2025-05-10 网络出版日期:2025-05-20

Preparation of waterborne pigment paste and its application in curtain fabrics

  1. 1.College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou 310018, China; 2. Innovation Center of Advanced Textile Technology (Jianhu Laboratory), Shaoxing 312030, China; 3. Zhejiang Provincial Key Laboratory of Green Cleaning Technology and Washing Supplies, Lishui 323000, China
  • Published:2025-05-10 Online:2025-05-20

摘要: 为明确水性涂料色浆中分散剂与黏合剂间的协同分散机制,通过筛选不同种类的分散剂和黏合剂,制备了一系列水性涂料色浆。同时,采用丝网印花技术,调控黏合剂和增稠剂的添加量、焙烘温度和水性颜料色浆含量,制备了一系列彩色印花织物。借助纳米级激光粒度仪和透射电子显微镜等仪器对比分析了彩色窗帘K/S值、干湿摩擦色牢度、透气率、硬挺度、断裂强力、紫外防护和耐紫外老化等性能。结果表明:具有芳香环结构的分散剂与黏合剂之间存在强π-π相互作用,可形成协同分散效应;涂料色浆制备的印花织物K/S值最高(4.4),干湿摩擦牢度可达5级,透气性提升至157.76 mm/s,断裂强力提高至1700.90 N,硬挺度增加至8.92 cm。此外,该印花织物还展现了极佳紫外防护性能(TUPF:95.3±0.7,TUVA:4.7%±0.2%),且其褪色率仅为商品化染料的1/2,在窗帘织物领域展现了良好的应用潜力。研究结果为设计开发高性能窗帘织物着色用的水性涂料色浆提供新策略。

关键词: 水性涂料色浆, 协同分散, 着色效果, 耐候性, 印花织物

Abstract: Colored curtains not only give a sense of pleasure and comfort for residents through color adjustment, but also offer strong UV protection. Currently, pigment printing and dyeing are the two most commonly used methods for preparing colored curtains. Compared with dyeing, pigment printing has advantages such as a wider range of applicability and being environmentally friendly. Meanwhile, pigments excel over dyes in terms of light resistance, chemical resistance, and weatherability, thus enhancing the weather resistance of curtain fabrics. However, an adhesive needs to be added due to the lack of affinity between pigments and fibers. The addition of adhesive can easily lead to secondary aggregation of color paste in waterborne dispersible pigments, which results in poor color uniformity in printing and affecting aesthetics and functionality of colored curtains.
To clarify the synergistic dispersion mechanism between dispersants and adhesives in waterborne pigment paste, a series of waterborne pigment paste was prepared by screening different types of dispersants and adhesives, and color printed fabrics were prepared by using screen printing technology. By using a nanoscale laser particle sizer and a transmission electron microscope, the particle size and morphology of waterborne pigment paste were characterized. Comparative analyses were conducted on the K/S value, color fastness to dry and wet rubbing, air permeability, stiffness, breaking strength, UV protective performance, and UV light fastness of the colored curtain fabrics. The results indicated that dispersants containing aromatic ring structures had strong π-π interactions with adhesives, which could form a synergistic dispersion effect. Compared with the commercial dye/pigment coloring effects, the printed fabrics prepared with the pigment paste in this experiment exhibited the highest K/S value (4.4), achieved a color fastness rating of 5, improved breathability to 157.76 mm/s, and increased breaking strength to 1,700.90 N and stiffness to 8.92 cm. Additionally, the printed fabrics demonstrated excellent UV protection performance (TUPF: 95.3±0.7 and TUVA: 4.7%± 0.2%), and their fading rate was only half of commercial dyes, showcasing good application potential in the field of curtain fabrics.
The research will not only provide technical support for the optimization of key process parameters in nano-based waterborne coatings but also offer certain theoretical foundations and practical guidance for the scientific design of high-UV-resistant colored curtain fabrics.

Key words: waterborne pigment paste , synergistic dispersion, coloring effect, weathering resistance, printed fabric

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