气相沉积法构筑的超疏水化妆棉及其油水分离性能

doi:10.19398/j.att.202204027

摘要/Abstract

摘要： 以甲基三甲氧基硅烷为改性剂,通过气相沉积法制备了超疏水亲油化妆棉,利用扫描电子显微镜和傅立叶红外光谱对化妆棉的微观形貌和化学结构进行表征,探究了该化妆棉的油水分离性能。结果表明:改性剂水解后与化妆棉高分子链中的羟基发生脱水反应,成功地实现了化妆棉的疏水化改性,改性化妆棉的水接触角为151°,油接触角为0°,具有良好的疏水亲油性,能选择性吸附水中的油污,油水分离效率高,分离通量为22918 L/(h·m²),且重复使用10次后分离效率仍高于95.3%。重力驱动下可以有效实现乳液的油水分离,对常见生活污水及强酸、强碱水溶液均具有良好的防污效果,并具有良好的自清洁性能,在油水分离领域具有广阔的应用前景。

关键词: 气相沉积法, 超疏水, 油水分离, 自清洁

Abstract: The superhydrophobic and oleophilic cosmetic cotton pads were prepared via vapour phase deposition method by using methyltrimethoxysilane as the modifier. The microscopic morphology and chemical structure of modified cotton pads were characterised by SEM and FT-IR, and the oil-water separation performance of the cotton pads was investigated. The results indicated that the hydrolytic modifier and the hydroxyl group in the polymer chain of the cosmetic cotton pads underwent a dehydration reaction, which resulted in the hydrophobic modification of the cotton pads. The water contact angle of the modified cotton pads was 151° and the oil contact angle was 0°, with good hydrophobic and oleophilic properties. The modified cotton pads can selectively adsorb oil in water with high oil-water separation efficiency, the separation flux is 22918 L/(h·m²), and the separation efficiency is still higher than 95.3% after 10 times of repeated use. The oil-water separation of emulsions can be effectively achieved under gravity drive. The modified cotton pads exhibit good anti-fouling effect on common domestic sewage, acid or alkali aqueous solutions, and show good self-cleaning performance, thus having broad application prospects in the field of oil-water separation.

Key words: vapour phase deposition method, superhydrophobicity, oil-water separation, self-cleaning

中图分类号:

TB332

邱心妮, 郭韫淇, 张楠涛, 王欣, 石嘉威, 区嘉雨, 李泳, 余传明. 气相沉积法构筑的超疏水化妆棉及其油水分离性能[J]. 现代纺织技术, 2022, 30(6): 157-165.

QIU Xinni, GUO Yunqi, ZHANG Nantao, WANG Xin, SHI Jiawei, OU Jiayu, LI Yong, YU Chuanming. Fabrication of superhydrophobic cosmetic cotton pads by vapour phase deposition method and its oil-water separation[J]. Advanced Textile Technology, 2022, 30(6): 157-165.

参考文献

[1] 屈孟男,侯琳刚,何金梅,等.功能化超疏水材料的研究与发展[J].化学进展,2016,28(12):1774-1787.
QU Mengnan, HOU Lingang, HE Jinmei, et al. Research and development of functional superhydrophobic materials[J]. Progress in Chemistry, 2016, 28(12): 1774-1787.
[2] 佟威,熊党生.仿生超疏水表面的发展及其应用研究进展[J].无机材料学报,2019,34(11):1133-1144.
TONG Wei, XIONG Dangsheng. Bioinspired superhy-drophobic materials: Progress and functional application[J]. Journal of Inorganic Materials, 2019, 34(11): 1133-1144.
[3] BAI Y X, ZHANG H P, SHAO Y Y, et al. Recent progresses of superhydrophobic coatings in different application fields: An overview[J]. Coatings, 2021, 11(2): 116.
[4] CASSIE A B D, BAXTER S. Wettability of porous surfaces[J]. Transactions of the Faraday Society, 1944, 40: 546-551.
[5] BARTHLOTT W, NEINHUIS C. Purity of the sacred lotus, or escape from contamination in biological surfaces[J]. Planta, 1997, 202(1): 1-8.
[6] FENG L, LI S, Li Y, et al. Super-hydrophobic surfaces: from natural to artificial[J]. Advanced Materials, 2002, 14(24): 1857-1860.
[7] GAO X F, JIANG L. Water-repellent legs of water striders[J]. Nature, 2004, 432: 36.
[8] ZHENG Y M, GAO X F, JIANG L. Directional adhesion of superhydrophobic butterfly wings[J]. Soft Matter, 2007, 3(2): 178-182.
[9] 徐兰芳,王锋,于英豪,等.超亲水/水下超疏油膜功能材料及其研究进展[J].材料导报,2020,34(17):17105-17114.
XU Lanfang, WANG Feng, YU Yinghao, et al. Research progress on superhydrophilic/underwater superoleophobic functional membrane materials[J]. Materials Reports, 2020, 34(17): 17105-17114.
[10] WANG S T, LIU K S, YAO X, et al. Bioinspired surfaces with superwettability: New insight on theory, design, and applications[J]. Chemical Reviews, 2015, 115(16): 8230-8293.
[11] SU B, TIAN Y, JIANG L. Bioinspired interfaces with superwettability: From materials to chemistry[J]. Journal of American Chemical Society, 2016, 138(6): 1727-1748.
[12] SI Y F, DONG Z C, JIANG L. Bioinspired designs of superhydrophobic and super-hydrophilic materials[J]. ACS Central Science, 2018, 4(9): 1102-1112.
[13] SHANMUGAVELAYUTHAM G, ANUPRIYANKA T, BHAGYASHREE P, et al. Plasma surface modification of cotton fabric by using low pressure plasma[J]. IEEE Transactions on Plasma Science, 2021, 49(2): 497-501.
[14] ZHONG L Q, GONG X. Phase separation-induced superhydrophobic polylactic acid films[J]. Soft Matter, 2019, 15(6): 9500-9506.
[15] ZHU Y, HE Y, ZHANG J F, et al. Preparation of large-scale, durable, superhydrophobic PTFE films using rough glass templates[J]. Surface and Interface Analysis, 2017, 49(13): 1422-1430.
[16] LONG M Y, PENG S, DENG W S, et al. Robust and thermal-healing superhydrophobic surfaces by spin-coating of polydimethylsiloxane[J]. Journal of Colloid and Interface Science, 2017, 508: 18-27.
[17] GUO J C, WANG C D, YU H B, et al. Preparation of a wear-resistant, superhydrophobic SiO₂/silicone-modified polyurethane composite coating through a two-step spraying method[J]. Progress in Organic Coatings, 2020, 146: 105710.
[18] RAMAN A, JAYAN J S, DEERAJ B D S, et al. Electrospun nanofibers as effective superhydrophobic surfaces: A brief review[J]. Surfaces and Interfaces, 2021, 24: 101140.
[19] KIM Y, LEE W, AGN Y. Metal ion-assisted fabrication of hierarchically structured superhydrophobic surfaces on Mg plates[J]. 2018, Bulletin of the Korean Chemical Society, 2018, 39(6): 837-839.
[20] KE C, ZHANG C H, WU X G, et al. Highly transparent and robust superhydrophobic coatings fabricated via a facile sol-gel process[J]. Thin Solid Films, 2021, 723: 138583.
[21] WAN H R, HE T T, JU X Z, et al. Rapid fabrication of superhydrophobic surface on magnesium alloy with excellent corrosion-resistant and self-cleaning properties[J]. Bulletin of the Chemical Society of Japan, 2021, 94(3): 961-965.
[22] MA N, CHENG D, ZHANG J Q, et al. A simple, inexpensive and environmental-friendly electrochemical etching method to fabricate superhydrophobic GH4169 surfaces[J]. Surface & Coatings Technology, 2020, 399: 126180.
[23] LIAO K J, ZHU J Y. A facile and cost-effective method to prepare a robust superhydrophobic RTV silicone coating[J]. Coatings, 2021, 11(3): 312.
[24] CELIK N, TORUN I, RUZI M, et al. Fabrication of robust superhydrophobic surfaces by one-step spray coating: Evaporation driven self-assembly of wax and nanoparticles into hierarchical structures[J]. Chemical Engineering Journal, 2020, 396: 125230.
[25] ZHANG N, QI F F, TIAN S H, et al. Bottom-up and up-down strategy to obtain the highly porous polystyrene foam for oily water remediation[J]. Separation and Purification Technology, 2021, 262: 118233.
[26] KIM D C, HA Y G. Cross-linked organic-inorganic hybrid composite films for one-step fabrication of robust superhydrophobic surfaces[J]. Journal of Nanoscience and Nanotechnology, 2020, 20(2): 1028-1032.
[27] ZHANG F, SHI Z W, CHEN L S, et al. Porous superhydrophobic and superoleophilic surfaces prepared by template assisted chemical vapor deposition[J]. Surface & Coatings Technology, 2017, 315: 385-390.
[28] ATTAR M, KHAJAVIAN E, HOSSEINPOUR S, et al. Fabrication of micro-nano-roughened surface with superhy-drophobic character on an aluminium alloy surface by a facile chemical etching process[J]. Bulletin of Materials Science, 2019, 43(1): 31.
[29] 薛鑫宇,尹正生,蒋永锋,等.碳钢表面防腐超疏水TiO₂/PDMS涂层的制备及性能[J].中国表面工程,2021,34(4):53-59.
XUE Xinyu, YIN Zhengsheng, JIANG Yongfeng, et al. Preparation and properties of TiO₂/PDMS anticor-rosion superhydrophobic coating on carbon steel[J]. China Surface Engineering, 2021, 34(4): 53-59.
[30] FENG C C, ZHANG Z Y, LI J, et al. A bioinspired, highly transparent surface with dry-style antifogging, antifrosting, antifouling, and moisture self-cleaning properties[J]. Macromolecular Rapid Communications, 2019, 40(6): 1800708.
[31] 赵一鉴,燕则翔,苏建民,等.仿生防冰表面研究进展[J].表面技术,2021,50(10):29-39.
ZHAO Yijian, YAN Zexiang, SU Jianmin, et al. Research progress of biomimetic anti-icing Surface[J]. Surface Technology, 2021, 50(10): 29-39.
[32] 张春来,王潇,吴银涛,等.超疏水表面水下减阻技术研究进展[J].功能材料与器件学报,2021,27(5):445-455.
ZHANG Chunlai, WANG Xiao, WU Yintao, et al. Research onunderwater drag reduction technology of super-hydrophobic surfaces[J]. Journal of Functional Materials and Devices, 2021, 27(5): 445-455.
[33] LI Z, MILIONIS A, ZHENG Y, et al. Superhydrophobic hemostatic nanofiber composites for fast clotting and minimal adhesion[J]. Nature Communications, 2019, 10: 5562.
[34] ZHAO C M, CHEN L, YU C M, et al. Fabrication of hydrophobic NiFe₂O₄@poly(DVB-LMA) sponge via a Pickering emulsion template method for oil/water separation[J]. Soft Matter, 2021, 17(8): 2327-2339.
[35] QING Y Q, LONG C, AN K, et al. Sandpaper as template for a robust superhydrophobic surface with self-cleaning and anti-snow/icing performances[J]. Journal of Colloid and Interface Science, 2019, 548: 224-232.
[36] 贺雅卿.湿巾发展概况和个人护理用湿巾新趋势[J].造纸信息,2020(5):47-51.
HE Yaqing. Overview and new trends of wet wipes[J]. China Paper Newsletters, 2020(5): 47-51.
[37] LIU K S, DU J X, WU J T, et al. Superhydrophobic gecko feet with high adhesive forces towards water and their bio-inspired materials[J]. Nanoscale, 2012, 4(3): 768-772.
[38] ZHOU Y Y, MA Y B, SUN Y Y, et al. Facile preparation of robust superhydrophobic cotton fabric for ultrafast removal of oil from contaminated waters[J]. Environmental Science and Pollution Research, 2020, 27(17): 21202-21212.
[39] CHEN P C, XU Z K. Mineral-coated polymer membranes with superhydrophilicity and underwater superoleophobicity for effective oil/water separation[J]. Scientific Reports, 2013, 3: 2776.
[40] ZHANG W B, SHI Z, ZHANG F, et al. Superhydrophobic and superoleophilic PVDF membranes for effective separation of water-in-oil emulsions with high flux[J]. Advanced Materials, 2013, 25(14): 2071-2076.
[41] CHAKRABARTY B, GHOSHAL A K, PURKAIT M K. Ultrafiltration of stable oil-in-water emulsion by polysulfone membrane[J]. Journal of Membrance Science, 2008, 325(1) 427-437.
[42] TAI M H, GAO P, TAN B Y L, et al. Highly efficient and flexible electrospun carbon-silica nanofibrous membrane for ultrafast gravity-driven oil-water separation[J]. ACS Applied Materials & Interfaces, 2014, 6(12): 9393-9401.
[43] SHI H, HE Y, PAN Y, et al. A modified musselinspired method to fabricate TiO₂ decorated superhydrophilic PVDF membrane for oil/water separation[J]. Journal of Membrance Science, 2016, 506: 60-70.
[44] CHEN Y E,WANG N, GUO F Y, et al. A Co₃O₄ nano-needle mesh for highly efficient, high-flux emulsion separation[J]. Journal of Materials Chemistry A, 2016, 4(31): 12014-12019.
[45] WANG J T, WANG H F. Separation and purification technology easily enlarged and coating-free underwater superoleophobic fabric for oil/water and emulsion separation via a facile NaClO₂ treatment[J]. Separation and Purification Technology, 2018, 195: 358-366.
[46] CUI J Y, ZHOU Z P, XIE A T, et al. Bio-inspired fabrication of superhydrophilic nanocomposite membrane based on surface modification of SiO₂ anchored by polydopamine towards effective oil-water emulsions separation[J]. Separation and Purification Technology, 2019, 209: 434-442.
[47] DU L, QUAN X, FAN X F, et al. Electro-responsive carbon membranes with reversible superhydrophobicity/superhydrophilicity switch for efficient oil/water separation[J]. Separation and Purification Technology, 2019, 210: 891-899.
[48] SHAHABADI S M S, BRANT J A. Bio-inspired superhydrophobic and superoleophilic nanofibrous membranes for non-aqueous solvent and oil separation from water[J]. Separation and Purification Technology, 2018, 210: 587-599.
[49] BAI X G, SHEN Y Q, TIAN H F, et al. Facile fabrication of superhydrophobic wood slice for effective water-in-oil emulsion separation[J]. Separation and Purification Technology, 2019, 210: 402-408.
[50] LI X P, CAO M, SHAN H T, et al. Facile and scalable fabrication of superhydrophobic and superole-ophilic PDMS-co-PMHS coating on porous substrates for highly effective oil/water separation[J]. Chemical Engineering Journal, 2018, 358: 1011-1113.