现代纺织技术 ›› 2024, Vol. 32 ›› Issue (4): 10-20.

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B-PDA-G/PDMS导热绝缘材料的制备及应用

  

  1. 1.天津工业大学纺织科学与工程学院,天津 300380;2.山东省产品质量检验研究院,山东济南 250102;3.山东德润新材料科技有限公司,山东德州 253011
  • 出版日期:2024-04-10 网络出版日期:2024-04-12

Preparation and application of B-PDA-G/PDMS thermally conductive insulating materials

  1. 1. School of Textile Science and Engineering, Tiangong University, Tianjin 300380, China; 2. Shandong Institute for Product Quality Inspection, Jinan 250102, China; 3. Shandong Derun New Material Technology Co., Ltd., Dezhou 253011, China
  • Published:2024-04-10 Online:2024-04-12

摘要: 为解决可穿戴电子设备中的散热问题,开发了一种高导热、高电绝缘性能的柔性热管理材料。通过选用氮化硼(BN)和石墨烯纳米片(GNPs)作为杂化导热填料,选取聚多巴胺(PDA)对杂化导热填料表面进行改性,然后与聚二甲基硅氧烷(PDMS)混合,采用热压法制备了不同填料质量分数的B-PDA-G/PDMS导热绝缘膜。利用傅里叶变换红外光谱、X射线光电子能谱和扫描电镜等表征手段,探究填料B-PDA-G与单一BN对PDMS膜导热性能的影响,并评估其在纺织领域的应用可行性。结果表明:B-PDA-G/PDMS膜在低填料质量分数时能够保持良好的力学性能、电绝缘性和导热性能。当BN与GNPs的质量比为5∶5,填料质量分数为30%时 B-PDA-G/PDMS导热绝缘膜的面内导热率最高可达7.63 W/(m·K),相较于BN/PDMS和纯PDMS膜分别提高了2.8倍和27.3倍。B-PDA-G/PDMS作为封装材料应用于电热织物中表现出良好的导热和散热性能,表明其在柔性可穿戴设备和电子器件的热管理中应用潜力巨大。

关键词: 表面改性, 聚二甲基硅氧烷(PDMS), 聚多巴胺(PDA), 导热绝缘, 热管理

Abstract: With the continuous improvement of people's living standards, people have put forward more diverse requirements for the performance of clothing, and it has shown great market prospects. As the future development trend of wearable devices, the heat dissipation of electronic devices has gradually become the key to research and application in various fields, especially in the textile field. If there is no effective heat dissipation, overheating will seriously reduce the performance and reliability of the equipment. Polymers are often used in thermal management materials for their advantages of good processability, high relative molecular mass, low water absorption, high resistivity, high breakdown voltage, corrosion resistance and low cost. However, the inherent low thermal conductivity (0.2~0.5 W/(m·K)) of the polymer matrix generally limits its thermal applications. Usually, thermally conductive fillers such as the inorganic ceramic fillers of aluminum oxide (Al2O3), aluminum nitride(AlN), and zinc oxide(ZnO) are added to the polymer matrix to improve the thermal conductivity of polymers. The addition of these high-density ceramic fillers usually results in low compatibility with the polymer, poor dispersion, high loading, and unsatisfactory improvement of the thermal conductivity of the composites.
To solve the heat dissipation problem in wearable electronic devices, flexible thermal management materials with high thermal conductivity and electrical insulation properties were obtained. Boron nitride (BN) and graphene nanoparticles (GNPs) were selected as hybridized thermally conductive fillers, and B-PDA-G/PDMS flexible thermally conductive and insulating films with different filler contents were prepared by hot-pressing method after surface modification of the hybridized fillers by polydopamine (PDA) and mixing with polydimethylsiloxane (PDMS) matrix. Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) were used to investigate the effects of filler B-PDA-G and single BN on improving the thermal conductivity of PDMS membrane materials and to assess the feasibility of their application in the textile field. The results show that the B-PDA-G/PDMS composite membranes can maintain good mechanical properties, electrical insulation and thermal conductivity at low filler filling. When the mass ratio of BN to GNPs is 5:5 and the mass fraction of filler is 30%, the in-plane thermal conductivity of B-PDA-G/PDMS can reach up to 7.63 W/(m-K), which is 2.8 times and 27.3 times higher compared to BN/PDMS materials and pure PDMS materials, respectively. 
By coating the flexible thermally conductive and insulating composites into the electrothermal fabric as the encapsulation coating, it is found that B-PDA-G/PDMS has better heat transfer and dissipation ability compared with BN/PDMS at the safe heating temperature of human body, which demonstrates its broad application prospect in smart wearable products.

Key words: surface modification, polydimethylsiloxane (PDMS), polydopamine (PDA), thermal conductivity and insulation, thermal management

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