靛蓝清洁染色技术的研究进展

摘要/Abstract

摘要： 为应对靛蓝染料应用带来的环境问题，开发靛蓝清洁染色技术成为当前的研究重点。首先聚焦于靛蓝还原过程，介绍了靛蓝绿色还原剂的开发、电化学还原和生物还原靛蓝技术的原理及研究进展；随后聚焦还原过程之外的其他靛蓝清洁染色技术，综述了靛蓝无氧泡沫染色技术、原位染色技术、氮气保护染色技术以及非水介质染色技术的研究现状；最后对靛蓝清洁染色技术研究进行了展望。多种途径的靛蓝清洁染色技术不断被应用，持续的工艺优化和多种清洁染色技术的融合发展是未来发展的趋势。

关键词: 靛蓝清洁染色技术, 电化学还原, 泡沫染色, 非水介质染色技术, 氮气保护染色, 原位染色

Abstract: In response to the environmental issues caused by the use of indigo dyes, the development of clean indigo dyeing technologies has become a focal point of research. In recent years, technologies such as green reducing agents for indigo, electrochemical reduction, biological reduction of indigo, indigo foam dyeing without oxygen, in-situ dyeing, nitrogen-protected dyeing, and non-aqueous medium dyeing have been developed. This article reviews the principles, development, and challenges of these technologies and provides an outlook for future indigo clean dyeing technology. The review found that one of the major challenges in developing green alternative reducing agents lies in identifying reducing agents that can match the high reduction potential of indigo and activate its reducing capacity, while ensuring recyclability. Biological reduction technology is still in its early stages and requires improvements in the catalytic efficiency of enzymes or cells, along with considerations of their stability, reusability, adaptability to the environment, and specificity, to meet the needs of industrial production. In electrochemically reducing indigo, improving reduction efficiency, current efficiency, and rate, as well as controlling hydrogen evolution side reactions, are crucial for the application of this technology. Additionally, addressing the separation and recovery of mediators in indirect electrocatalytic reduction is crucial for reducing material loss and enhancing economic and environmental benefits. Some of the core innovations in other novel indigo clean dyeing methods focus on precisely controlling the early oxidation process of indigo leuco dye or abandoning the traditional reduction-dyeing mechanism. These innovations not only significantly reduce resource consumption but also greatly enhance dyeing quality. However, in practical applications, these advanced technologies still face a series of challenges. Looking forward, advancements in mechanical and chemical engineering will bring innovative opportunities for clean indigo dyeing. Indigo clean dyeing technology is expected to integrate electrochemical reduction, biological reduction, green reducing agents, and pre-reduced indigo products to form environmentally friendly and efficient solutions. At the same time, methods for controlling the early oxidation of indigo leuco dye and dyeing in non-aqueous media will be further optimized to enhance dyeing effects. On the other hand, process optimization and cost control will be key focuses of future research. Although new methods are environmentally friendly and have shown promising results in industrial demonstrations, equipment costs, operational complexity, and market acceptance remain challenges for their widespread adoption. Future research will concentrate on process optimization to reduce the use of water, energy, and chemicals, so as to reduce costs and promote the widespread application of clean dyeing technology to achieve a green transformation in indigo dyeing.

Key words: indigo clean dyeing technology, electrochemical reduction, foam dyeing, non-aqueous medium dyeing technology, nitrogen-protected dyeing, in-situ dyeing

中图分类号:

TS193.6

朱合金, 陈佳豪, 文水平, 刘旭峰, 陈桂春. 靛蓝清洁染色技术的研究进展[J]. 现代纺织技术.

参考文献

[1]易菁源, 裴刘军, 张红娟, 等. 无水少水染色技术发展及应用分析[J]. 纺织导报, 2023(4): 70-74.

YI J Y, PEI L J, ZHANG H J, et al. Development and application analysis of less water and anhydrous dyeing[J]. China Textile Leader, 2023(4): 70-74.

[2] LI X, WANG K, WANG M, et al. Sustainable electrochemical dyeing of indigo with Fe(Ⅱ)-based complexes[J]. Journal of Cleaner Production, 2020, 276: 123251.

[3]李瑞卿, 王伟, 魏炳举, 等. 新型环保牛仔浆染纱靛蓝染色[J]. 印染, 2019, 45(23): 26-28.

LI R Q, WANG W, WEI B J, et al. Innovative indigo dyeing of denim yarn[J]. China Dyeing & Finishing, 2019, 45(23): 26-28.

[4]NAIR G P, SHAH R C. Sodium borohydride in vat dyeing[J]. Textile Research Journal, 1970, 40(4): 303-312.

[5]TSUDA T, FUJII T, KAWASAKI K, et al. Copper(i)-catalysed conjugate reduction of αβ-unsaturated carbonyl compounds by lithium aluminium hydride[J]. Journal of the Chemical Society, Chemical Communications, 1980(21): 1013-1014.

[6]MEKSI N, KECHIDA M, MHENNI F. Cotton dyeing by indigo with the borohydride process: Effect of some experimental conditions on indigo reduction and dyeing quality[J]. Chemical Engineering Journal, 2007, 131(13): 187-193.

[7]MEKSI N, BEN TICHA M, KECHIDA M, et al. New catalysts for the borohydride dyeing process[J]. Industrial & Engineering Chemistry Research, 2010, 49(24): 12333-12338.

[8]王梦倩. 电化学还原催化体系研究[D]. 石家庄: 河北科技大学, 2020.

WANG M Q. Study on catalytic system of electrochemical reduction of indigo[D]. Shijiazhuang: Hebei University of Science and Technology, 2020.

[9]刘祥霞, 卢嘉杰, 杜文琴, 等. 葡萄糖还原植物靛蓝的机理及染色方法[J]. 印染, 2012, 38(16): 9-12.

LIU X X, LU J J, DU W Q, et al. Reduction mechanism of plant indigo with glucose and its dyeing process[J]. China Dyeing & Finishing, 2012, 38(16): 9-12.

[10]BEN TICHA M, MEKSI N, DRIRA N, et al. A promising route to dye cotton by indigo with an ecological exhaustion process: A dyeing process optimization based on a response surface methodology[J]. Industrial Crops and Products, 2013, 46: 350-358.

[11] SAIKHAO L, SETTHAYANOND J, KARPKIRD T, et al. Green reducing agents for indigo dyeing on cotton fabrics[J]. Journal of Cleaner Production, 2018, 197: 106-113.

[12]王文静, 李龙春, 祖倚丹, 等. 靛蓝的果糖环保还原染色工艺[J]. 印染助剂, 2022, 39(3): 47-52.

WANG W J, LI L C, ZU Y D, et al. Environment-friendly fructose reduction dyeing process of indigo[J]. Textile Auxiliaries, 2022, 39(3): 47-52.

[13]MEKSI N, BEN TICHA M, KECHIDA M, et al. Using of ecofriendly α-hydroxycarbonyls as reducing agents to replace sodium dithionite in indigo dyeing processes[J]. Journal of Cleaner Production, 2012, 24: 149-158.

[14]段双庚, 卢彦, 李俊, 等. 二羟基丙酮还原糖属性的实验确认[J]. 生物学通报, 2021, 56(7): 39-42.

DUAN S G, LU Y, LI J, et al. Experimental confirmation of reducing sugar properties of dihydroxyacetone[J]. Bulletin of Biology, 2021, 56(7): 39-42.

[15]BEN T, MEKSI N, DRIRA N, et al. The synergetic effect of α-hydroxycarbonyls mixtures used as green reducing agent on the indigo dyeing process[J]. Chemical Industry and Chemical Engineering Quarterly, 2014, 20(4): 463-470.

[16]BLACKBURN R S, BECHTOLD T, JOHN P. The development of indigo reduction methods and pre-reduced indigo products[J]. Coloration Technology, 2009, 125(4): 193-207.

[17]黄旭, 张炜栋. 靛环保还原技术的研究进展[J]. 印染, 2023, 49(1): 74-78.

HUANG X, ZHANG W D. Research progress of environment-friendly reduction methods of indigo[J]. China Dyeing & Finishing, 2023, 49(1): 74-78.

[18]汪媛, 陆涛, 张聪, 等. 以抗坏血酸为还原剂的靛蓝染色工艺研究[J]. 常州大学学报(自然科学版), 2018, 30(6): 9-16.

WANG Y, LU T, ZHANG C, et al. Study on the dyeing process of indigo with ascorbic acid as reductant[J]. Journal of Changzhou University (Natural Science Edition), 2018, 30(6): 9-16.

[19]廖欢, 吴艳丽, 周亭, 等. 枯草芽孢杆菌酶的还原性能及用于靛蓝染料还原[J]. 湖南工程学院学报(自然科学版), 2020, 30(1): 65-68.

LIAO H, WU Y L, ZHOU T, et al. The reduction performance of bacillus subtilis enzyme and its application to indigo dye reduction[J]. Journal of Hunan Institute of Engineering (Natural Science Edition), 2020, 30(1): 65-68.

[20]CHAKRABORTY J. MAZUMDAR P, 许科能. 以碱性脂肪酶为还原催化剂的棉织物靛蓝染色[J]. 国际纺织导报, 2021, 49(10): 19-22.

CHAKRABORTY J. MAZUMDAR P, XU K N. Indigo dyeing of cotton using alkaline lipase as reduction catalyst[J]. Melliand China, 2021, 49(10): 19-22.

[21]JENNIFER KAN S B, HUANG X, GUMULYA Y, et al. Genetically programmed chiral organoborane synthesis[J]. Nature, 2017, 552(7683): 132-136.

[22]刘昆. 基于生物还原的植物靛蓝染色研究[D]. 天津: 天津工业大学, 2019.

LIU K. Study on plant indigo dyeing based on bioreduction[D]. Tianjin: Tiangong University, 2019.

[23]成美林, 江雨, 李政, 等. 内源电子介体自介导靛全细胞生物还原染色[J]. 针织工业, 2022(8): 31-36.

CHENG M L, JIANG Y, LI Z, et al. Study on indigo whole-cell reduction dyeing mediated by endogenous electron mediators[J]. Knitting Industries, 2022, 8: 31-36.

[24] YI C, TAN X, BIE B, et al. Practical and environment-friendly indirect electrochemical reduction of indigo and dyeing[J]. Scientific Reports, 2020, 10(1): 4927.

[25] ROESSLER A, DOSSENBACH O, RYS P. Electrocatalytic hydrogenation of indigo process optimization and scale-up in a flow cell[J]. Journal of The Electrochemical Society, 2003, 150(1): D1-D5.

[26] BOŽIČ M, KOKOL V. Ecological alternatives to the reduction and oxidation processes in dyeing with vat and sulphur dyes[J]. Dyes and Pigments, 2008, 76(2): 299-309.

[27] 高淑珍. 超声波染色的动力学研究[J]. 印染, 2002, 28(12): 4-6.

GAO S Z. Investigation on ultrasound dyeing kinetics[J]. China Dyeing & Finishing, 2002, 28 (12): 4-6.

[28] 李海风. 的电化学还原研究[D]. 杭州: 浙江工业大学, 2014.

LI H F. Study on electrochemical reduction of indigo[D]. Hangzhou: Zhejiang University of Technology, 2014.

[29] 刘超. 还原染料直接电化学还原染色及应用[D]. 北京: 北京服装学院, 2017.

LIU C. Direct electrochemical reduction dyeing with vat dyes and its application[D]. Beijing: Beijing Institute of Clothing Technology, 2017.

[30] 陈胜洲, 谢惠英, , 等. 还原染料电化学还原染色方法研究进展[J]. 广东化工, 2008, 35(7): 65-68.

CHEN S Z, XIE H Y, LIU Z L, et al. Development of electrochemical methods for the reduction of vat dyes[J]. Guangdong Chemical Industry, 2008, 35(7): 65-68.

[31] 王梦倩, 李晓燕, 姚继明. 电化学技术在染色中的应用(二)[J]. 印染, 2019, 45(16): 51-56.

WANG M Q, LI X Y, YAO J M. Application of electrochemical technology in dyeing processes (Ⅱ)[J]. China Dyeing & Finishing, 2019, 45(16): 51-56.

[32] SHEDLOVSKY T. Electrochemistry in biology and medicine[M]. New York: Wiley, 1955.

[33] 汪康康. 电化学染色体系的研究[D]. 石家庄: 河北科技大学, 2019.

WANG K K. Study on electrochemical dyeing system of indigo[D]. Shijiazhuang: Hebei University of Science and Technology, 2019.

[34] ROESSLER A, DOSSENBACH O, MARTE W, et al. Electrocatalytic hydrogenation of vat dyes[J]. Dyes and Pigments, 2002, 54(2): 141-146.

[35] CLAUDIA M, JOERG B, GUENTHER H, et al. Method for electrochemical reduction of reducible dyes[P]. World Patent, 2001. 1: 46497.

[36]梅华, 陈晓蓉, 张统. 一种靛蓝加氢合成氢化靛蓝的催化剂、其制备方法及应用: CN106975483A[P]. 2017-07-25.

MEI H, CHEN X R, ZHANG T. A catalyst for the hydrogenation of indigo to hydrogenated indigo, its preparation method and application: China, 201710311146. 1[P]. 2017-05-25.

[37]LIU Z, YU X, LI J, et al. Electrocatalytic hydrogenation of indigo by NiMoS: energy saving and conversion improving[J]. Dalton Transactions, 2023, 52(46): 17438-17448.

[38]李贺. 棉织物在电解池体系中染色的机理及其性能研究[D]. 武汉: 武汉纺织大学, 2021.

LI H. Study on dyeing mechanism and properties of cotton fabric in electrolytic cell system[D]. Wuhan: Wuhan Textile University, 2021.

[39]谢惠英, 陈胜洲, 董新法, 等. 靛蓝的间接电化学还原及其动力学[J]. 化学反应工程与工艺, 2008, 24(6): 516-522.

XIE H Y, CHEN S Z, DONG X F, et al. Mediator indirect eelectrochemical reduction of indigo and its kinetics[J]. Chemical Reaction Engineering and Technology, 2008, 24(6): 516-522.

[40]马淳安, 周亚明, 徐颖华, 等. 铁-三乙醇胺媒质中靛蓝的间接电化学还原[J]. 物理化学学报, 2010, 26(3): 589-594.

MA C A, ZHOU Y M, XU Y H, et al. Indirect electrochemical reduction of indigo using Fe-triethonolamine[J]. Acta Physico-Chimica Sinica, 2010, 26(3): 589-594.

[41]王清芝. 以Fe(Ⅲ)—草酸—葡萄糖酸钙为的间接电化学还原染色工艺研究[D]. 上海: 东华大学, 2012.

WANG Q Z. Study on indirect electrochemical reduction dyeing process with Fe (Ⅲ)-oxalic acid-calcium gluconate as medium[D]. Shanghai: Donghua University, 2012.

[42]王梦倩, 李晓燕, 姚继明. 靛蓝染料间接电化学还原技术的发展和现状(一)[J]. 印染, 2019, 45(10): 53-55.

WANG M Q, LI X Y, YAO J M. Development and current situation of indirect electrochemical reduction technology for indigo dyestuffs(I)[J]. China Dyeing & Finishing, 2019, 45(10): 53-55.

[43]汪康康, 李晓燕, 姚继明. Fe(Ⅱ)基协同络合体系下靛蓝电化学还原染色[J]. 针织工业, 2019(7): 46-51.

WANG K K, LI X Y, YAO J M. Electrochemical reduction dyeing of indigo under Fe(II)-based complex complexation system[J]. Knitting Industries, 2019(7): 46-51.

[44]ABDELILEH M, MANIAN A P, RHOMBERG D, et al. Calcium-iron-D-gluconate complexes for the indirect cathodic reduction of indigo in denim dyeing: A greener alternative to non-regenerable chemicals[J]. Journal of Cleaner Production, 2020, 266: 121753.

[45]周晶晶, 左丹英, 易长海. 电化学还原靛蓝隐色体染色性能[J]. 印染助剂, 2020, 37(12): 24-26.

ZHOU J J, ZUO D Y, YI C H. Dyeing properties of indigo leuco after electrochemical reduction[J]. Textile Auxiliaries, 2020, 37(12): 24-26.

[46]赖宇坤, 王炜. 环保型电化学还原染色工艺的研究[J]. 印染助剂, 2011, 28(5): 30-34.

LAI Y K, WANG W. Study on environmental protection electrochemical reduction dyeing process[J]. Textile Auxiliaries, 2011, 28(5): 30-34.

[47]BECHTOLD T, PHAM T. Production scale test for indirect cathodic reduction of indigo opens a route for greener denim[J]. Sustainable Materials and Technologies, 2023, 37: e00699.

[48]TAN X D, XIONG W, ZHANG J, et al. Indirect electrochemical reduction of indigo and dyeing[J]. Key Engineering Materials, 2018, 773: 379-383.

[49]ROESSLER A, JIN X. State of the art technologies and new electrochemical methods for the reduction of vat dyes[J]. Dyes and Pigments, 2003, 59(3): 223-235.

[50]费良, 殷允杰, 王潮霞. 新型泡沫染色技术[J]. 印染助剂, 2020, 37(11): 1-4.

FEI L, YIN Y J, WANG C X. Novel foam dyeing technology[J]. Textile Auxiliaries, 2020, 37(11): 1-4.

[51]ZHU D, WAN Z, ZHAO X, et al. Foaming indigo: An efficient technology for yarn dyeing[J]. Dyes and Pigments, 2022, 197: 109862.

[52]PERIYASAMY A P, PERIYASAMI S. Critical review on sustainability in denim: A step toward sustainable production and consumption of denim[J]. ACS Omega, 2023, 8(5): 4472-4490.

[53]WANG K, WANG M, LV W, et al. Optimization and assessment on indirect electrochemical reduction of indigo[J]. Pigment & Resin Technology, 2019, 49(2): 154-162.

[54]WANG K, DING W, LUO Q, et al. Cleaner dyeing technology for denim fabrics with excellent utilization of indigo based on inert gas protection[J]. ACS Sustainable Chemistry & Engineering, 2022, 10(48): 16009-16018.

[55]WANG K, MENG Y, LUO Q, et al. An ultrasound-assisted nitrogen protection system for sustainable indigo dyeing of cotton fabrics[J]. Textile Research Journal, 2023, 93(13/14): 3355-3367.

[56]姜秀增. 靛蓝染料清洁生产技术的研究进展[J]. 轻纺工业与技术, 2018, 47(7): 61-68.

JIANG X Z. Research progress on clean production technology of indigo dye[J]. Light and Textile Industry and Technology, 2018, 47(7): 61-68.

[57]安源. 新型非水介质染色技术原理研究[D]. 杭州: 浙江理工大学, 2022.

AN Y. Study on the principle of new non-aqueous medium dyeing technology[D]. Hangzhou: Zhejiang Sci-Tech University, 2022.

[58]朱振旭. 活性染料在非极性介质中染色及机理研究[D]. 杭州：浙江理工大学, 2017.

ZHU Z X. Study on dyeing mechanism of reactive dyes in nonpolar media[D]. Hangzhou: Zhejiang Sci-Tech University, 2017.

[59]樊杰. 非水介质体系中棉织物的活性染料染色性能及机理研究[D]. 杭州: 浙江理工大学, 2021.

FAN J. Study on dyeing properties and mechanism of cotton fabric with reactive dyes in non-aqueous media[J]. Hanzhou: Zhejiang Sci-Tech University, 2021.

[60]FU C, TAO R, WANG J, et al. Water-saving aftertreatment of reactive dyed cotton fabrics in D5 medium[J]. The Journal of the Textile Institute, 2016, 107(6): 719-723.

[61]李栋. 棉纤维的靛蓝染料/D5体系一次染深色技术研究[D]. 杭州: 浙江理工大学，2016.

LI D. Study on primary dyeing technology of cotton fiber with indigo dye/D5 system[D]. Hangzhou: Zhejiang Sci-Tech University, 2016.

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