阴离子型抗静电剂的合成及其性能

现代纺织技术 ›› 2023, Vol. 31 ›› Issue (2): 177-.

阴离子型抗静电剂的合成及其性能

1.绍兴文理学院浙江省清洁染整技术研究重点实验室，浙江绍兴312000； 2.绍兴瑞康生物科技有限公司，浙江绍兴312000； 3.浙江天圣化纤有限公司，浙江绍兴312000

收稿日期:2022-07-14 出版日期:2023-03-10 网络出版日期:2023-03-23
作者简介:虞美雅(1996—)，女，浙江东阳人，硕士研究生，主要从事纺织材料与纺织品设计方面的研究。
基金资助:
绍兴市科技专项(2019B21001)

Synthesis of the anionic antistatic agent and its property research

1. Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing University, Shaoxing 312000, China; 2.Shaoxing Ruikang Biotechnologies Co., Ltd., Shaoxing 312000, China; 3. Zhejiang Tiansheng Chemical Fiber Co., Ltd., Shaoxing 312000, China

Received:2022-07-14 Published:2023-03-10 Online:2023-03-23

摘要/Abstract

摘要： 为丰富高分子抗静电剂的组成并探讨其在涤纶材料上的应用，选用多种功能单体合成了非离子和阴离子型两类抗静电剂，并将其与聚对苯二甲酸乙二醇酯（PET）切片熔融共混制备了抗静电PET注塑样品，表征了非离子型抗静电剂的热学以及抗静电性能，重点考察了阴离子型抗静电剂中的磺酸盐组分对抗静电剂的热学性能、抗静电性能的影响以及阴离子型抗静电剂质量分数对PET基体的抗静电性能、表面亲水性能以及力学性能的影响。研究结果表明：非离子以及阴离子型抗静电剂具有较好的热稳定性；阴离子型抗静电剂的抗静电效果优于非离子型抗静电剂，当添加的磺酸盐摩尔分数为14%时，阴离子型抗静电剂的抗静电效果相对最优；当阴离子型抗静电剂质量分数达到20%时，PET注塑样品的表面电阻率下降了4个数量级，表面接触角下降了50.81%，其抗静电性能以及表面亲水性能得到显著提高，但力学性能有所下降。

关键词: 阴离子型抗静电剂, 热学性能, 抗静电性能, PET材料

Key words: anionic antistatic agent, thermal property, antistatic property, PET material

中图分类号:

TQ325.2

虞美雅, Rahmatulloev Kishvar, 毛丽娟, 吴晶瑾, 沈国建, 邹专勇. 阴离子型抗静电剂的合成及其性能[J]. 现代纺织技术, 2023, 31(2): 177-.

YU Meiya, RAHMATULLOEV Kishvar, MAO Lijuan, WU Jingjin, SHEN Guojian, ZOU Zhuanyong. Synthesis of the anionic antistatic agent and its property research[J]. Advanced Textile Technology, 2023, 31(2): 177-.

参考文献

[1] LI R, SI J J, TANG P. Enhancement of electrostatic charge dissipation properties of polymers by a sustained-release effect of mesoporous silica nanoparticles[J]. Polymers for Advanced Technologies, 2016, 27(5): 615-622.
[2] SI J J, TANG P. Influence of antistatic agent encapsulated into functionalized mesoporous silica on antistatic properties of polystyrene[J]. International Journal of Polymeric Materials and Polymeric Biomaterials, 2017, 67(12): 745-753.
[3] 刘训堃. 低表面电阻永久型抗静电剂PEBAX®[J]. 塑料助剂, 2011(1): 45-46.
LIU Xunkun. Low surface resistance permanent antistatic agentPEBAX®[J]. Plastics Additives, 2011(1): 45-46.
[4]李含. 丹尼斯克（Danisco）公司推出了用于包装薄膜的高效抗静电剂[J]. 塑料助剂, 2011(1): 58.
LI Han. High-efficiency antistatic agents for packaging films introduced by Danisco company[J]. Plastics Additives, 2011(1): 58.
[5] HAUAMANN K. Permanent antistatic agent offers long term performance for films and containers[J]. Plastics, Additives and Compounding, 2007, 9(3): 40-42.
[6] 翁永华, 汪理文, 丁贤麟. 一种永久型高分子抗静电剂及其制备方法: CN105085812A[P]. 2015-11-25.
WENG Yonghua, WANG Liwen, DING Xianlin. A permanent polymer antistatic agent and its preparation method: CN105085812A[P]. 2015-11-25.
[7]赖树兴. 一种阳离子/非离子复合高分子抗静电剂: CN107541001A[P]. 2018-01-05.
LAI Shuxing. A cationic/nonionic composite polymer antistatic agent: CN107541001A[P]. 2018-01-05.
[8]吴中心. 一种具有永久抗静电且可熔融直纺的导电纤维专用料: CN108796643A[P]. 2018-11-13.
WU Zhongxin. A special material for conductive fiber with permanent antistatic and melt direct spinning: CN108796643A[P]. 2018-11-13.
[9] FU Y, WANG J, ZHAO G, et al. Preparation and pro-perties of poly(ether-ester-amide)/poly(acrylonitr-ile-co-butadiene-co-styrene) antistatic blends[J]. Journal of Applied Polymer Science, 2011, 122(1): 12-18.
[10] XU X, XIAO H N, GUAN Y, et al. Permanent antistatic polypropylene based on polyethylene wax/polypropylene wax grafting sodium acrylate[J]. Journal of Applied Polymer Science, 2013, 127(2): 959-966.