现代纺织技术 ›› 2023, Vol. 31 ›› Issue (3): 225-236.
出版日期:
2023-05-10
网络出版日期:
2023-05-26
作者简介:
韩雨兰(1998—),女,江苏盐城人,硕士研究生,主要从事水性聚氨酯及超纤革染色方面的研究。
基金资助:
Published:
2023-05-10
Online:
2023-05-26
摘要: 与传统溶剂型聚氨酯相比,水性聚氨酯(WPU)大大减少了有机溶剂的使用,可有效降低环境污染,正越来越受到人们的关注。然而,WPU中亲水基团的引入会影响其力学性能,限制了WPU产品的使用范围。本文对WPU组成结构和力学性能之间的关系进行了阐述,并对WPU染色方面的研究现状做了介绍和总结,以期为水性聚氨酯超纤革的开发提供借鉴和参考。
中图分类号:
韩雨兰, 宋兵, 李春霖, 杜远远, 牛家嵘. 水性聚氨酯组成结构与力学性能的关系及其染色性能的研究进展[J]. 现代纺织技术, 2023, 31(3): 225-236.
HAN Yulan, SONG Bing, LI Chunlin, DU Yuanyuan, NIU Jiarong. Research progress on the relationship between composition structure and mechanical properties of waterborne polyurethane and its dyeing properties[J]. Advanced Textile Technology, 2023, 31(3): 225-236.
[1] 刘长伟, 史颖, 马驰,等. 异氰酸酯硬段对聚氨酯结构及性能的影响[J]. 高分子材料科学与工程, 2021, 37(3): 79-84. LIU Changwei, SHI Ying, MA Chi, et al. Effect of isocyanate hard segment on structure and property of polyurethane[J]. Polymer Materials Science & Engineering, 2021,37(3): 79-84. [2] 凡永利, 郑水蓉, 苏航, 等. 水性聚氨酯改性及其应用研究进展[J]. 中国胶粘剂, 2011, 20(5): 56-60. FAN Yongli, ZHENG Shuirong, SU Hang, et al. Research progress of modification and application of waterborne polyurethane[J]. China Adhesives 2011, 20(5): 56-60. [3] ZHANG J J, HUANG H, MA J, et al. Preparation and properties of corrosion-resistant coatings from waterborne polyurethane modified epoxy emulsion[J]. Frontiers in Materials, 2019, 6: 185. [4] 杜壮. 羊毛织物防毡缩整理及羊毛角蛋白的生物医用研究[D]. 上海: 东华大学, 2019. DU Zhuang. Research on Anti-taping Treatment of Wool Fabric and Biomedical Application of Wool Keratin[D]. Shanghai: Donghua university, 2019. [5] FANG C Q, ZHOU X, YU Q, et al. Synthesis and characterization of low crystalline waterborne polyurethane for potential application in water-based ink binder[J]. Progress in Organic Coatings, 2014, 77(1): 61-71. [6] 谢珍, 杜壮, 阎克路. 蛋白酶和有机硅改性聚氨酯联合防毡缩工艺[J]. 毛纺科技, 2017, 45(9): 27-33. XIE Zhen, DU Zhuang, YAN Kelu. Anti-felting process of wool fabric by protease and polysiloxane modified waterborne polyurethane[J]. Wool Textile Journal, 2017, 45(9): 27-33. [7] 丁会会. 功能性羊绒针织制品聚氨酯整理剂的研发与应用[D]. 西安: 西安工程大学, 2020. DING Huihui. Development and Application of Functional Cashmere Knitted Polyurethane Finishing Agent[D]. Xi′an: Xi'an Polytechnic University, 2020. [8] 张冰, 张弛, 肖升木, 等. 改性蛋白酶的制备及其在羊毛防毡缩整理中的应用[J]. 纺织学报, 2012, 33(5): 74-80. ZHANG Bing, ZHANG Chi, XIAO Shengmu, et al. Preparation of modified protease and its application on antifelting finishing of wool[J]. Journal of Textile Research, 2012, 33(5): 74-80. [9] 杜鹃. 聚氨基甲酸酯弹性纤维的染色性能及染色原理研究[D]. 苏州: 苏州大学, 2001. DU Juan. A Study on the Behaviours and Principles of Dyeing for Polyurethane Fibers[D]. Suzhou: Suzhou University, 2001. [10] SHAMSI R, MAHYARI M, KOOSHA M. Synthesis of CNT-polyurethane nanocomposites using ester-based polyols with different molecular structure: Mechanical, thermal, and electrical properties[J]. Journal of Applied Polymer Science, 2017, 134(10): 13. [11] 张赛楠. 芳香族水性聚氨酯材料的合成及其性能研究[D]. 哈尔滨: 黑龙江大学, 2018. ZHANG Sainan. Synthesis and Properties of Aromatic Waterborne Polyurethane Materials[D]. Harbin: Heilongjiang University, 2018. [12] 邱峻, 韦军, 王宝总, 等. 亲水性封闭型芳香族异氰酸酯交联剂的合成及性能研究[J]. 聚氨酯工业, 2011, 26(6): 39-42. QIU Jun, WEI Jun, WANG Baozong, et al. Synthesis and performance research of waterborne blocked aromatic isocyanate crosslinking agent[J]. Polyurethane industry, 2011, 26(6): 39-42. [13] 崔海世. 无溶剂型脂肪族聚氨酯合成与性能研究[D]. 长春: 吉林大学, 2008. CUI Haishi. Study on the Preparation and Properties of Aliphatic Polyurethane without Imprgnant[D]. Changchun: Jilin University, 2008. [14] 张基智. 脂环族双组分水性聚氨酯材料的合成及固化研究[D]. 哈尔滨: 黑龙江大学, 2018. ZHANG Jizhi. Study on Synthesis and Curing of Aliphatic Cyclic Two-component Aqueous Polyurethane[D]. Harbin: Heilongjiang University, 2018. [15] 夏会华. 水性聚氨酯性能的影响因素[D]. 合肥: 安徽大学, 2013. XIA Huihua. Influencing Factors of Properties of Waterborne Polyurethane[D]. Hefei: Anhui University, 2013. [16] YUAN F, LIU W B, Yang F, et al. Preparation and properties of MDI-based polyester polyurethane elastomer[J]. Polymers & Polymer Composites, 2014, 22(3): 341-346. [17] 常伟林, 王建伟, 池俊杰, 等. 二聚酸二异氰酸酯在水性聚氨酯中的应用进展[J]. 化学推进剂与高分子材料, 2017, 15(1): 35-39. CHANG Weilin, WANG Jianwei, CHI Junjie, et al. Application progress of dimer acid diisocyanate in waterborne polyurethane[J]. Chemical Propellants and Polymer Materials, 2017, 15(1): 35-39. [18] 高喜平, 王勃, 曹光宇, 等. 异佛尔酮二异氰酸酯分子中异氰酸酯基团活性比较[J]. 河南科技大学学报(自然科学版), 2009, 30(2): 101-104,115. GAO Xiping, WANG Bo, CAO Guangyu, et al. Active comparison of isocyanates in isophorone diisocyanatek[J]. Journal of Henan University of Science and Technology(Natural Science Edition), 2009, 30(2): 101-104,115. [19] 陈卓. 六亚甲基二异氰酸酯固化剂的合成及结构表征[D]. 广州: 华南理工大学, 2014. CHEN Zhuo. The Synthesis and Characterization of HDI-based Curing Agent[D]. Guangzhou: South China University of Technology, 2014. [20] BARIKANI M, EBRAHIMI M V, MOHAGHEGH S M S. Influence of diisocyanate structure on the synthesis and properties of ionic polyurethane dispersions[J]. Polymer-Plastics Technology and Engineering, 2007, 46(11): 1087-1092. [21] 冼文琪. 二氧化碳基多元醇(PPCD)及水性聚氨酯的合成与应用研究[D]. 广州: 广东工业大学, 2021. XIAN Wenqi. Synthesis and Application of CO2 based Polyols(PPCD) and Waterborne Polyurethane[D]. Guangzhou: Guangdong University of Technology, 2021. [22] 石磊, 杨浩, 沈连根, 等. 无溶剂聚氨酯合成革技术的研究进展[J]. 现代纺织技术, 2021, 29(1): 76-81. SHI Lei, YANG Hao, SHEN Liangen, et al. Research progress of solvent-free polyurethane synthetic leather technology[J]. Advanced Textile Technology, 2021, 29(1): 76-81. [23] SUN Z, FAN H J, Chen Y, et al. Synthesis of self-matting waterborne polyurethane coatings with excellent transmittance[J]. Polymer International, 2018, 67(1): 78-84. [24] 庞灿. 聚酯多元醇合成工艺研究及其在水性聚氨酯塑料涂层中的应用[D]. 合肥: 合肥工业大学, 2017. PANG Cai. Study on Synthesis of Polyester Polyol and Its Application in Waterborne Polyurethane Plastic Coatings[D]. Hefei: Hefei University of Technology, 2017. [25] 郭旭东. 基于羟基磺酸型亲水扩链剂制备高固含量水性聚氨酯及其性能研究[D]. 西安: 陕西科技大学, 2021. GUO Xudong. Preparation and Performance of High solid Content Waterborne Polyurethane Based on Hydroxysulfonic Acid Hydrophilic Chain Extender[D]. Xi′an: Shaanxi University of Science and Technology, 2021. [26] 张淼. 侧链胺基型阳离子扩链剂的合成及其合成水性聚氨酯的研究[D]. 合肥: 安徽大学, 2020. ZHANG Miao. Synthesis of Side Chain Amino Type Cationic Chain Extender and Study on Synthesis of Waterborne[D]. Hefei: Anhui university, 2020. [27] 叶青萱. 亲水基团对水性聚氨酯性能的影响[J]. 聚氨酯工业, 2007, 22(6): 1-5. YE Qingxuan. Effect of hydrophilic radicals on property of waterborne polyurethane[J]. Polyurethane industry, 2007, 22(6): 1-5. [28] HONARKAR H, BARMAR M, BARIKANI M. New sulfonated waterborne wolyurethane dispersions: Preparation and characterization[J]. Journal of Dispersion Science and Technology, 2016, 37(8): 1219-1225. [29] 曾俊, 王武生, 阮德礼, 等. DMBA与DMPA聚氨酯乳液主要性能比较[J]. 皮革化工, 1999, 16(5): 19-22. ZENG Jun, WANG Wusheng, RUAN Deli, et al. Comparison between main properties of polyurethane dispersions based on DMBA and DMPA [J]. Leather and Chemicals, 1999, 16(5): 19-22. [30] Zhang Q Q, Lin X Q, Chen W S, et al. Applications of characterization methods in polyurethane materials: analysis of microphase-separated structures[J]. Applied Spectroscopy Reviews, 2022, 57(2): 153-176. [31] 薛振华. 水性聚氨酯中不同二元醇结构对性能的影响[D]. 济南: 齐鲁工业大学, 2019. XUE Zhenhua. A Thesis Submitted for the Application of the Master’s Degree of Engineering[D]. Jinan: Qilu University of Technology, 2019. [32] 徐恒志. 硬段含量和类型对水性聚氨酯性能的影响[D]. 合肥: 安徽大学, 2012. XU Hengzhi. Influence of Hard Segment Content and Type on the Performance of Waterborne Polyurethane[D]. Hefei: Anhui University, 2012. [33] XIAO Y, ZHAO H B, WU B, et al. Preparation and characterization of waterborne polyurethane based on diphenylmethane diisocyanate-50[J]. Advances in Polymer Technology, 2018, 37(2): 596-605. [34] 王柯, 彭娅, 王燕. 硬段含量对脂肪族阴离子水性聚氨酯性能的影响[J]. 化工进展, 2010, 29(1): 119-123. WANG Ke, PENG Ya, WANG Yan. Effect of hard segment content on the properties of aliphatic anionic waterborne polyurethanes[J]. Chemical Industry and Engineering Progress, 2010, 29(1): 119-123. [35] ORGILES-CALPENA E, ARAN-AIS F, TORRO-PALAU A M, et al. Influence of the chain extender nature on adhesives properties of polyurethane dispersions[J]. Journal of Dispersion Science and Technology, 2012, 33(1-3): 147-154. [36] GARCIA P V, COLERA M, IWATA Y, et al. Incidence of the polyol nature in waterborne polyurethane dispersions on their performance as coatings on stainless steel[J]. Progress in Organic Coatings, 2013, 76(12): 1726-1729. [37] LEE H T, WU S Y, JENG R J. Effects of sulfonated polyol on the properties of the resultant aqueous polyurethane dispersions[J]. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 2006, 276(1-3): 176-185. [38] LIU X H, HONG W, CHEN X D. Continuous production of water-borne polyurethanes: A Review[J]. Polymers, 2020, 12(12): 2875. [39] HU L Q, PU Z J, ZHONG Y Q, et al. Effect of different carboxylic acid group contents on microstructure and properties of waterborne polyurethane dispersions[J]. Journal of Polymer Research, 2020, 27(5): 9. [40] QIU F X, ZHANG J L, WU D M, et al. Waterborne polyurethane and modified polyurethane acrylate composites[J]. Plastics Rubber and Composites, 2010, 39(10): 454-459. [41] 刘思彤. 含氟丙烯酸酯/环氧树脂复合改性水性聚氨酯的制备及性能研究[D]. 长春: 长春工业大学, 2021. LIU Sitong. Preparation and Properties of Waterborne Polyurethane Modified by Fluorinated Acrylate/Epoxy Resin Composite[D]. Changchun: Changchun University of Technology, 2021. [42] 王芳芳, 钱年龙, 商杭, 等. 硅改性疏水型水性聚氨酯的制备及性能研究[J]. 中国皮革, 2021, 50(5): 55-63. WANG Fangfang, QIAN Nianlong, SHANG Hang. Preparation and properties of silicon modified hydrophobic waterborne polyurethane[J]. China Leather, 2021, 50(5): 55-63. [43] 张晓静. 有机硅改性水性聚氨酯的制备及性能探究[D]. 杭州: 浙江大学, 2021. ZHANG Xiaojing. Preparation and Properties of Silicone Modified Waterborne Polyurethane[D]. Hangzhou: Zhejiang University, 2021. [44] 王雪. 有机氟和交联双重改性水性聚氨酯的制备及性能研究[D]. 长春: 长春工业大学, 2020. WANG Xue. Study on the Preparation and Properties of Organic Fluorine and Crosslinked Double Modified Waterborne Polyurethane[D]. Changchun: Changchun University of Technology, 2020. [45] LIM C H, CHOI H S, NOH S T. Surface modification with waterborne fluorinated anionic polyurethane dispersions[J]. Journal of Applied Polymer Science, 2002, 86(13): 3322-3330. [46] 兰芬芬. 聚氨酯改性水性环氧树脂及其在防腐涂料中的应用[D]. 合肥: 安徽大学, 2021. LAN Fenfen. Polyurethane Modified Waterborne Epoxy Resin and Its Application in Anticorrosive Coatings[D]. Hefei: Anhui university, 2021. [47] 赵明恩. 合成革用水性聚氨酯/环氧树脂/丙烯酸酯IPN结构构筑及性能研究[D]. 青岛: 青岛科技大学, 2019. ZHAO Ming’en. Structuralconstruction and Properties of Waterborne Polyurethane/Epoxy Resin/Acrylate IPN for Synthetic Leather[D]. Qingdao: Qingdao University of Science and Technology, 2019. [48] 丁晓丹. 纳米SiO2改性水性聚氨酯的制备及性能研究[D]. 长春: 长春工业大学, 2020. DING Xiaodan. Study on Preparation and Properties of Waterborne Polyurethane Modified Polyurethane by Nano-SiO2[D]. Changchun: Changchun University of Technology, 2020. [49] 宋永华. 水性聚氨酯基纳米复合材料的制备及其性能研究[D]. 西安: 西安理工大学, 2021. SONG Yongha. Preparation and Properties of Waterborne Polyurethane-Based Nanocomposites[D]. Xi′an: Xi'an University of Technology, 2021. [50] WU G F, LI Y C, YANG Z H, et al. Preparation and characterization of glucose and sulfamate double-modified biodegradable waterborne polyurethane[J]. Chemistryselect, 2021, 6(31): 8140-8149. [51] TRAVINSKAYA T, SAVELYEV Y, MISHCHUK E. Waterborne polyurethane based starch containing materials: Preparation, properties and study of degradability[J]. Polymer Degradation and Stability, 2014, 101: 102-108. [52] TRET'YAKOVA A E, SAFONOV V V, YUSINA A Y. Study of processes of dyeing polyurethane fibres by various classes of dyes[J]. Fibre Chemistry, 2013, 44(5): 284-287. [53] LEE S K, LEE H Y, KIM S D. Dyeing properties of mixture of ultrafine nylon and polyurethane with different types of dye[J]. Fibers and Polymers, 2013, 14(12): 2020-2026. [54] 潘笑娟, 王利民, 杨柳波, 等. 超细PA/PU合成革用酸性染料的染色性能研究[J]. 染料与染色, 2006, 43(4): 27-31, 40. PAN Xiaojuan, WANG Limin, YANG Liubo, et al. A Study on dyeing properties of superfine fiber PA/PU syntheticleather[J]. Dyestuffs and Coloration, 2006, 43(4): 27-31, 40. [55] 胡雪丽, 马兴元, 郭梦亚, 等. 固色剂SLA在超细纤维合成革染色中的应用研究[J]. 中国皮革, 2014, 43(23): 24-27. HU Xueli, MA Xingyuan, GUO Mengya, et al. Application of fixing agent SLA in microfiber synthetic leather dyeing[J]. China Leather, 2014, 43(23): 24-27. [56] 李峥嵘, 涂伟萍, 赖应光, 等. 超细锦纶PU革增深匀染剂Intratex LPUA[J]. 印染, 2010, 36(21): 27-29. LI Zhengrong, TU Weiping, LAI Yingguang, et al. Deepening and leveling agent intratex LPUA for supermicro PA/PU leatheroid [J]. China Dyeing & Finishing, 2010, 36(21): 27-29. [57] 白刚, 刘艳春. 苯甲醇对超细纤维合成革染色性能的影响[J]. 纺织学报, 2011, 32(1): 78-81. BAI Gang, LIU Yanchun. Effect of benzoic alcohol on dyeing properties of microfiber synthetic leather[J]. Journal of Textile Research, 2011, 32(1): 78-81. [58] 李金华, 李晓霞, 张悦. 超纤锦纶PU合成革的涂料染色工艺研究[J]. 皮革与化工, 2014, 31(5): 28-30. LI Jinhua, LI Xiaoxiao, ZHANG Yue. Research on pigment dyeing process for microfiber Nylon PU synthetic leather[J]. Leather and Chemicals, 2014, 31(5): 28-30. [59] 胡忠杰. 超纤染色牢度的工艺优化[J]. 印染, 2018, 44(15): 32-34. HU Zhongjie. Process optimization for improving color fastness of microfiber leather[J]. China Dyeing & Finishing, 2018, 44(15): 32-34. [60] 强涛涛, 王晓芹, 王学川, 等. 水解胶原蛋白对超细纤维合成革基布染色性能影响的研究[J]. 功能材料, 2014, 45(14): 14066-14071. QIANG Taotao, WANG Xiaoqin, WANG Xuechuan, et al. Study on the effect of dyeing properties of microfiber synthetic leather base by hydrolyzed collagen[J]. Journal of Functional Materials, 2014, 45(14): 14066-14071. [61] 龚燕燕, 吉婉丽, 徐欣欣, 等. 易染色超细纤维合成革用聚氨酯树脂的研制[J]. 聚氨酯工业, 2007, 22(4): 34-37. GONG Yanyan, JI Wanli, XU Xinxin, et al. Study on the preparation of polyurethane resin applied in superfine synthetic leather[J]. Polyurethane Industry, 2007, 22(4): 34-37. [62] 张卫东. 易染色超细纤维合成革用聚氨酯树脂的合成与表征[D]. 上海: 华东理工大学, 2012. ZHANG Weidong. Preparation and Characterization of Easy Dying Polyurethane for Micro Fiber Leather[D]. Shanghai: East China University of Science and Technology, 2012. [63] 黄玲, 成松涛, 符晓兰. 壳聚糖/乙二醛交联体系对超细纤维合成革染色性能的影响[J]. 陕西科技大学学报(自然科学版), 2010, 28(4): 52-55. HUANG Ling, CHEN Songtao, FU Xiaolan. Influence of chitosan-glyoxal cross-link on performance of dyeing in superfine fiber synthetic leather[J]. Journal of Shaanxi University of Science and Technology (Natural Science Edition), 2010, 28(4): 52-55. [64] 祝彬. 超细纤维合成革用水性聚氨酯的研究进展[J]. 中国皮革, 2020, 49(4): 32-36. ZHU Bin. Research progress of waterborne polyurethane for superfine fiber synthetic leather[J]. China Leather, 2020, 49(4): 32-36 [65] ZHENG Y, ZHANG X Y, LI J P. Synthesis and photochromism properties of anionic waterborne polyurethane containing azobenzene chromophores[J]. Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 2015, 52(11): 942-949. [66] ZHAO J, HOU J H, CHAI C P, et al. Preparation and characterization of yellow waterborne polyurethane with 2,6-diaminoanthraquinone structure[J]. Polymer Testing, 2022, 106: 107451. [67] WANG Y L, JIN L Q. Preparation and characterization of self-colored waterborne polyurethane and its application in eco-friendly manufacturing of microfiber synthetic leather base[J]. Polymers, 2018, 10(3): 289. [68] WANG H H, TZAI G M, CHANG C C. Alkali reduction and reactive dye dyeing of T/N nonwoven fabrics dipped into silicon-containing, water-borne polyurethane[J]. Journal of Applied Polymer Science, 2005, 96(6): 2324-2335. [69] LIU R W, CHEN Y, FAN H J. Design, characterization, dyeing properties, and application of acid-dyeable polyurethane in the manufacture of microfiber synthetic eather[J]. Fibers and Polymers, 2015, 16(9): 1970-1980. |
[1] | 姬洪, 宋明根, 张玥, 陈康, 张玉梅. 共聚型阻燃聚酯工业丝的纺丝成形[J]. 现代纺织技术, 2023, 31(4): 56-62. |
[2] | 骆宣耀, 韦粤海, 马雷雷, 田伟, 祝成炎. 硅烷偶联剂改性对玄武岩纤维增强乙烯基酯树脂复合材料力学性能的影响[J]. 现代纺织技术, 2023, 31(4): 103-110. |
[3] | 施强, 石教学, 郑雄, 张须臻. 活化油剂及上油工艺对聚酯高强纤维性能影响[J]. 现代纺织技术, 2023, 31(3): 155-162. |
[4] | 宋佳丽, 李运景, 郝龙云. 有机颜料水性分散体系的制备及其对棉织物的染色性能[J]. 现代纺织技术, 2023, 31(3): 188-193. |
[5] | 陶丽珍, 周锁林, 廖兰兰. 金属长丝复合导电纱的纺制与性能[J]. 现代纺织技术, 2023, 31(2): 130-. |
[6] | 许亮, 沈林祺, 余志成, 王磊, 谢光远. 纯棉针织物荔枝核天然染料小浴比染色工艺及其性能[J]. 现代纺织技术, 2023, 31(1): 232-239. |
[7] | 谢治云, 李文斌, 张贺, 黄丛, 官思佳, 刘洋. 连续氧化铝纱线及其织物力学性能[J]. 现代纺织技术, 2022, 30(6): 88-94. |
[8] | 谢沉着, 邵晓莉, 赵强强, 何瑾馨. 磺化四苯乙烯荧光染料的合成及其发光性能[J]. 现代纺织技术, 2022, 30(6): 133-140. |
[9] | 郭晓曼, 贾丽霞, 刘冬志. 树脂固相合成甜菜色素衍生物对羊毛的染色性能[J]. 现代纺织技术, 2022, 30(6): 141-149. |
[10] | 王慧佳, 陈强, 易雨青, 施静雅, 李妮. 扩链时间对聚氨酯及其静电纺纳米纤维性能的影响[J]. 现代纺织技术, 2022, 30(5): 67-73. |
[11] | 聂磊, 李家炜, 严小飞, 戚栋明, 杨晓明, 李耀邦, 朱晨凯. 全降解玻璃纤维增强复合材料的制备及其性能[J]. 现代纺织技术, 2022, 30(5): 104-111. |
[12] | 徐天伟, 柴璐娜, 唐奇, 王成龙, 金淑兰, 陈冬梅, 郑今欢. 含生物可降解聚酯纤维雪尼尔纱的染色性能[J]. 现代纺织技术, 2022, 30(5): 188-196. |
[13] | 陈志薇, 张顺花. 呋喃基共聚酯PETT纤维的制备及其性能[J]. 现代纺织技术, 2022, 30(4): 102-107. |
[14] | 于海娟, 杨斌, 傅红平, 余志成, 王磊. 菝葜根天然染料对改性棉织物的染色性能[J]. 现代纺织技术, 2022, 30(4): 156-161. |
[15] | 于颖. 马钱苷结构修饰产物对真丝绸的染色性能[J]. 现代纺织技术, 2022, 30(4): 162-169. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||