现代纺织技术 ›› 2025, Vol. 33 ›› Issue (01): 51-57.

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蓝莓色素对改性纯棉纱布的染色性能

  

  1. 1.河北宁纺集团有限责任公司,河北邢台 055550;2.河北省应急防护面料产业技术研究院,河北邢台 055550
  • 出版日期:2025-01-10 网络出版日期:2025-02-18

Dyeing properties of blueberry pigment on modified cotton gauze

  1. 1. Hebei Ningfang Group Co., Ltd., Xingtai 055550, China; 2. Hebei Emergency Protective Fabric Industrial Technology Research Institute, Xingtai 055550, China
  • Published:2025-01-10 Online:2025-02-18

摘要: 为开发高档纯棉纱布染色产品,研究了蓝莓色素在纯棉纱布染色中的应用。针对蓝莓色素不易上染的特点,分析了壳聚糖、阳离子季铵盐、硅烷偶联剂KH550改性对纱布K/S值的影响,并对直接染色工艺参数(pH值、浴比、温度和时间)进行优化,另外还分析了媒染剂氯化镧、单宁酸、卡拉胶对纱布染色效果的影响,同时测试了染色纱布的色牢度、抗紫外性、吸湿导热性以及抗氧化性。结果表明:阳离子季铵盐改性纯棉纱布提高了蓝莓色素的上染能力;直接染色最优工艺为pH值8、温度50 ℃、时间30 min、浴比1∶40;氯化镧后媒染时纱布色深值较好;染色后纱布耐摩擦色牢度、耐水洗色牢度均能达到3级以上,吸湿导热性能下降,紫外防护性能和抗氧化性能得到改善。

关键词: 植物染料, 蓝莓色素;纯棉纱布;色牢度;抗紫外;抗氧化

Abstract: In recent years, with the improvement of people's health concept, eco-friendly textiles have been increasingly favored by consumers. Pure cotton gauze stands as a high-grade textile, which is made of natural cotton fiber through spinning and weaving. Pure cotton gauze has the advantages of soft feel, moisture absorption, breathability, skin-friendly and no static electricity. Therefore, it can be used as baby blanket, underwear, bath towel, clothing and bedding. Plant dyes, sourced widely and being green and biodegradable, are extensively used in textile dyeing and printing. Dyeing pure cotton gauze with natural plant dyes can not only minimize the potential harm of dyes to the human body but also enhance the added value, versatility, and eco-friendliness of the material.
To develop high-grade pure cotton gauze dyeing products, this paper focused on natural blueberry pigment dyes and pure cotton gauze as the primary research objects. Firstly, pure cotton gauze was modified by chitosan, cationic quaternary ammonium salt and silane coupling agent KH550. The K/S values of pure cotton gauze under different modification reagents were investigated respectively. Then, the direct dyeing process parameters (pH value, bath ratio, temperature and time) of pure cotton gauze were optimized to obtain a better dyeing process. Finally, to improve the color depth of pure cotton gauze, the effects of mordant (lanthanum chloride, tannic acid and carrageenan) and mordant dyeing methods (pre-mordant dyeing, syn-mordant dyeing and post-mordant dyeing) on the dyeing effect of gauze were studied. At the same time, the color fastness, UV resistance, moisture absorption, thermal conductivity, and oxidation resistance of dyed cotton gauze were tested.
The results show that cationic quaternary ammonium salt-modified cotton gauze can effectively improve the dyeing ability of blueberry pigment, and the dyeing effect is relatively good. The optimal conditions for direct dyeing of pure cotton gauze are: a pH value of 8, temperature at 50°C, duration of 30 minutes, and a bath ratio of 1:40. After mordant dyeing of pure cotton gauze with lanthanum chloride, the color depth value of the gauze increases. After dyeing, the color fastness to rubbing and washing of pure cotton gauze can reach more than grade 3, the moisture absorption and thermal conductivity are reduced, and the UV protection performance and oxidation resistance are improved.
The blueberry is a nutritious blue berry. Its primary components include cellulose, protein, anthocyanins, polyphenols, flavonoids, and other substances. Blueberries are known for their beauty-enhancing properties, ability to protect vision, and anti-aging benefits. Furthermore, they can be used to treat hypertension, hyperglycemia, and regulate intestinal flora. At present, there are few reports on the application of blueberry pigment in textiles. Further research is needed to broaden the application field of blueberry pigment.

Key words: plant dye, blueberry pigment, cotton gauze, color fastness, UV resistance, antioxidation

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