Preparation of TiO2 nanorod composite fabric and its photocatalytic and antibacterial properties

doi:10.19398/j.att.202105005

Abstract

Abstract: To prepare a functional fabric with photocatalytic and antibacterial properties, a flexible organic fabric coated by TiO₂ nanorod was prepared using TiCl₃ as Ti source through low-temperature hydrothermal method by growing TiO₂ nanorod vertically on the surface of polyester fabric. The structure and morphology of the composite fabric were characterized and analyzed using SEM, TEM, FTIR, XRD and XPS. Then, the photocatalytic properties of the composite fabric under ultraviolet light and the antibacterial properties under visible light were tested. The results show that the composite fabric is able to effectively degrade organic pollutants under ultraviolet light irradiation. Compared with commercial P25 nanoparticle-coated fabric, it has better photocatalytic properties. After visible light irradiation for 2 h, its antibacterial activity against Escherichia coli and Staphylococcus aureus exceeded 99%, indicating that the functional fabric prepared in this study has broad application prospects in photocatalytic degradation of organic pollutants and antibacterial performance.

Key words: fabric, TiO₂ nanorod, photocatalysis, antibacterial

摘要： 为制备具有光催化和抗菌性能的功能织物,采用低温水热法,使用TiCl₃为Ti源,在涤纶织物表面垂直生长TiO₂纳米棒,制备了包覆有TiO₂纳米棒的柔性有机织物。利用SEM、TEM、FTIR、XRD和XPS等对复合织物的结构和形貌进行表征和分析,并测试复合织物在紫外光下的光催化性能和可见光下的抗菌性能。结果表明:该复合织物在紫外光照射下可有效降解有机污染物,与商业化P25纳米颗粒涂覆织物相比较具有更好的光催化性能。可见光照射2 h后,对大肠杆菌和金黄色葡萄球菌具有大于99%的抗菌性。制备的功能织物在光催化降解有机污染物和抗菌方面具有广泛的应用前景。

关键词: 织物, TiO₂纳米棒, 光催化, 抗菌

CLC Number:

TB332

JIA Xueying, WANG Tao. Preparation of TiO₂ nanorod composite fabric and its photocatalytic and antibacterial properties[J]. Advanced Textile Technology, 2022, 30(3): 136-142.

贾雪莹, 王騊. TiO₂纳米棒复合织物的制备及其光催化和抗菌性能[J]. 现代纺织技术, 2022, 30(3): 136-142.

References

[1] 杨定勇,陈莉,殷翔芝,等.抗静电多功能纺织品的开发[J].纺织报告,2019(4):19-22.
YANG Dingyong, CHEN Li, YIN Xiangzhi, et al.Development of antistatic multifunctional textiles[J]. TextileReport, 2019(4):19-22.
[2] CHEN G, LI Y, BICK M, et al. Smart textiles for electricity generation[J]. Chemical Reviews, 2020, 120(8): 3668-3720.
[3] YETISEN A, QU H, MANBACHI A, et al. Nanotechno-logy in textiles[J]. ACS Nano, 2016, 10(3): 3042-3068.
[4] LI S, HUANG J, CHEN Z, et al. A review on special wettability textiles: Theoretical models, fabrication technologies and multifunctional applications[J]. Journal of Materials Chemistry A, 2017, 5(1): 31-55.
[5] 张雷,向龙玲,郝慧聪,等.TiO₂/陶粒光催化降解甲基橙研究[J].环境科学与管理,2011,36(7):99-101.
ZHANG Lei, XIANG Longling, HAO Huicong, et al. Photocatalytic degradation of methyl orange by TiO₂/ceramsite[J]. Environmental Science and Management, 2011, 36(7): 99-101.
[6] 许文涛,于岩,盛瑞,等.GO/TiO₂复合催化剂的制备及其光催化降解甲基橙[J].化工时刊,2017,31(1):5-8.
XU Wentao, YU Yan, SHENG Rui, et al. Preparation of GO/TiO₂ composite catalyst and its photocatalytic degradation of methyl orange [J]. Chemical Times, 2017, 31(1): 5-8.
[7] WEN W, WU J M, JIANG Y, et al. Titanium dioxide nanotrees for high-capacity lithium-ion microbatteries[J]. Journal of Materials Chemistry A, 2016, 4(27): 10593-10600.
[8] GE M, CAI J, IOCOZZIA J, et al. A review of TiO₂ nanostructured catalysts for sustainable H₂ generation[J]. International Journal of Hydrogen Energy, 2017, 42(12):8418-8449.
[9] GAO S W, HUANG J Y, LI S H, et al. Facile construction of robust fluorine-free superhydrophobic TiO₂@fabrics with excellent anti-fouling, water-oil separation and UV-protective properties[J]. Materials & Design, 2017, 128:1-8.
[10] YANG M P, LIU W Q, JIANG C, et al. Fabrication of superhydrophobic cotton fabric with fluorinated TiO₂ sol by a green and one-step sol-gel process[J]. Carbohydrate Polymers, 2018, 197(1):75-82.
[11] GIESZ P, MACKIEWICZ E, GROBELNY J, et al. Multifunctional hybrid functionalization of cellulose fabrics with AgNWs and TiO₂[J]. Carbohydrate Polymers, 2017, 177:397-405.
[12] WU J M, SONG X M, YAN M. Alkaline hydrothermal synthesis of homogeneous titania microspheres with urchin-like nanoarchitectures for dye effluent treatments[J]. Journal of Hazardous Materials, 2011, 194:338-344.
[13] 谢顺吉,张海坤,刘国栋,等.局部表面等离子体共振可调的MoO₃-x-TiO₂纳米复合物用于提高可见光下光催化还原CO₂的性能[J].催化学报,2020,41(7):1125-1131.
XIE Shunji, ZHANG Haikun, LIU Guodong, et al. Localized surface plasmon resonance-tunable MoO₃-x-TiO₂ nanocomposites for enhanced photocatalytic CO₂ reduction under visible light[J]. Chinese Journal of Catalysis, 2020, 41(7): 1125-1131.
[14] LI J M, WU T T, GUO M Z, et al. A facile solution route to deposit TiO₂ nanowire arrays on arbitrary substrates.[J]. Nanoscale, 2014, 6(6):3046-3050.
[15] SUN Z, KIM J H, LIAO T, et al. Continually adjustable oriented 1D TiO₂ nanostructure arrays with controlled growth of morphology and their application in dye-sensitized solar cells[J]. Crystengcomm, 2012, 14(17):5472-5478.
[16] 刘仁兵,刘朝辉,肖舟,等.TiO₂纳米棒阵列的制备及形貌控制[J].现代化工,2019,39(4):108-111,113.
LIU Renbing, LIU Zhaohui, XIAO Zhou, et al. Preparation and morphology control of TiO₂ nanorod arrays[J]. Modern Chemical Industry, 2019, 39(4): 108-111, 113.
[17] 孙凌显,包启富,刘昆,等.氧化铝基板上二氧化钛纳米棒薄膜的形貌及其润湿性的研究[J].中国陶瓷,2020,56(5):27-32.
SUN Lingxian, BAO Qifu, LIU Kun, et al. Morphology and wettability of TiO₂ nanorod thin films on alumina substrates[J]. China Ceramics, 2020, 56(5): 27-32.
[18] HOSONO E, FUJIHARA S, KAKIUCHI K, et al. Growth of submicrometer-scale rectangular parallelepiped rutile TiO2 films in aqueous TiCl3 solutions under hydrothermal conditions[J]. Journal of the American Chemical Society, 2004, 126(25):7790-7791.
[19] XIANG S, XU S, YUAN G, et al. 3D hierarchical golden wattle-like TiO₂ microspheres: Polar acetone-based solvothermal synthesis and enhanced water purification performance[J]. Crystengcomm, 2017, 19(16):2187-2194.
[20] FENG X, ZHAI J, JIANG L. The fabrication and switchable superhydrophobicity of TiO₂ nanorod films[J]. Angewandte Chemie International Edition, 2005, 44(32): 5115-5118.
[21] 陈雪莲,韦萌,潘喜强.金属离子掺杂对金红石型纳米TiO₂的稳定性影响[J].兵器材料科学与工程,2020,43(1):1-5.
CHEN Xuelian, WEI Meng, PAN Xiqiang. Effect of metal ion doping on the stability of rutile nano-TiO₂[J]. Ordnance Materials Science and Engineering, 2020, 43(1): 1-5.
[22] THOMS H, EPPLE M, FROBA M, et al. Metal diolates: Useful precursors for tailor-made oxides prepared at low temperatures[J]. Journal of Materials Chemistry, 1998, 8(6): 1447-1451.
[23] LI K, HUANG Z, ZENG X, et al. Synergetic effect of Ti³⁺ and oxygen doping on enhancing photoelectroche-mical and photocatalytic properties of TiO₂/g-C₃N₄ heterojunctions[J]. ACS Applied Materials & Interfaces. 2017, 9(13): 11577-11586.

Preparation of TiO₂ nanorod composite fabric and its photocatalytic and antibacterial properties

TiO₂纳米棒复合织物的制备及其光催化和抗菌性能

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	HU Yili, ZHOU Jiu. Influence of full-color weave in triple-weft jacquard fabric structure on surface texture [J]. Advanced Textile Technology, 2022, 30(5): 124-130.
[2]	MA Chen, JIN Xiaoke, TANG Shali, ZHU Chengyan. Evaluation method of unidirectional moisture conductivity of polyester woven fabrics [J]. Advanced Textile Technology, 2022, 30(5): 131-138.
[3]	WU Mingxing, WANGJinqian, GE Yanfang. Construction and properties of micro/nano water repellent surface of modified cotton fabrics [J]. Advanced Textile Technology, 2022, 30(5): 197-205.
[4]	JIANG Wuwei, LAI Zhongkai, XING Yajie, HAO Haitao, CHEN Xu, LI Yongqiang. Study on the effect of spandex colorant on the dyeing homochromaticity and color fastness of polyamide/spandex fabric [J]. Advanced Textile Technology, 2022, 30(5): 206-212.
[5]	TAN Wei, MA Mingbo, ZHOU Wenlong. Preparation of self-cleaning multifunctional cotton fabrics based on nano-Cs_0.33WO₃ and its properties [J]. Advanced Textile Technology, 2022, 30(5): 213-221.
[6]	ZHUGE Yina, LIU Fujuan. Review of antimicrobial materials with bionic micro-nano structure [J]. Advanced Textile Technology, 2022, 30(5): 222-234.
[7]	ZHANG Yingxin, XU Lei, WANG Dawei, LI Nan, YANG Yunfei. Research progress of fabric electrode in bioelectric signal monitoring [J]. Advanced Textile Technology, 2022, 30(4): 42-49.
[8]	SUN Xiao, WANG Jun, CHEN Tao, GAO Yang, LÜ Tianguang. Research on influencing factors of the protective performance for arc protection fabrics [J]. Advanced Textile Technology, 2022, 30(4): 61-69.
[9]	SCHEN Chunhui, XU Duo, LI Zhijiang, JI Qiang. Preparation and properties of hydrophobic-oleophylic composite cotton fabrics [J]. Advanced Textile Technology, 2022, 30(4): 115-123.
[10]	ZHANG Hui, LIU Xianfei, XU Jinguang. Design and properties of new flame retardant fabric for thermal protective clothing [J]. Advanced Textile Technology, 2022, 30(4): 134-141.
[11]	GE Yunping. Fabric image defect detection based on parallel comprehensive learning particle swarm optimization [J]. Advanced Textile Technology, 2022, 30(4): 142-148.
[12]	TANG Shali, CHEN Weilai, MA Chen. Design and simulation of multi bar warp knitted automobile roof fabric [J]. Advanced Textile Technology, 2022, 30(4): 149-155.
[13]	YU Haijuan, YANG Bin, FU Hongping, YU Zhicheng, WANG Lei. Dyeing properties of modified cotton fabric with Smilax china L. root dye [J]. Advanced Textile Technology, 2022, 30(4): 156-161.
[14]	LIU Yaqiong, LI Nan, LI Wen, WANG Lijun. Influence of clothing structure design on electromagnetic shielding effectiveness [J]. Advanced Textile Technology, 2022, 30(4): 193-199.
[15]	YU Ying. Effect of Loganin structure modified product on the dyeing property of pure silk [J]. Advanced Textile Technology, 2022, 30(4): 162-169.